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Bionanotechnology is a combination of three terms: “bios” meaning “life,” “nano” (origin in Greek) meaning “dwarf,” and “technologia” (origin in Greek—comprised of “techne” meaning “craft,” and “logia” meaning “saying”), which is a broad term dealing with the use and knowledge of humanity’s tools and crafts. Biomolecular Nanotechnology—or Bionanotechnology—is a term coined for the area of study...
Bulk quantities of polypyrrole nanofibers and nanospheres can be synthesized with a facile, one-step "green-nano" chemical oxidative polymerization approach, by simply using different reaction media.
In this article, we study dynamics of adsorbate island formation in a model plasma-condensate system numerically. We derive the generalized reaction-diffusion model for adsorptive multilayer system by taking into account anisotropy in transfer of adatoms between neighbor layers induced by electric field. It will be found that with an increase in the electric field strength, a structural transfo...
New and unknown electrocatalytic oxidation of water was found to occur on a nano-gold attached palladium electrode. Since the oxidation potential was negative enough to that of well-known normal oxidation of water to form O2, the direct use of water as a fuel, instead of alcohols, might be possible using the nano-gold/palladium electrode.
A simple and precise size measurement device of microparticles in liquid has been developed by using a narrow gap between a cylindrical lens and a flat glass wall, in which the distance of the gap is precisely determined by the diffraction Moiré pattern of irradiated light. Two different methods to transfer the particles toward the center line of the lens, a hydrodynamic flow mode and an electr...
Peptide derivatives of Aspirin (1 to 8) were synthesized by using Ac2O/AcOH reaction with Salicyclic acid. Aspirin was coupled with amino acid amide and dipeptide amide and tripeptide amide using its p-nitro phenyl (NP) ester. The ester (Aspirin–ONP) was prepared using p-nitro phenol and DCC in EtOAc and was precipitated using EtOH. The synthesis of dipeptide amides were carried out in solution...
N-Protonation of amides is critical in numerous biological processes, including amide bonds proteolysis and protein folding as well as in organic synthesis as a method to activate amide bonds towards unconventional reactivity. A computational model enabling prediction of protonation at the amide bond nitrogen atom along the C-N rotational pathway is reported. Notably, this study provides a blue...
The asymmetric unit of the title compound, C(7)H(7)NO(2)·0.5C(4)H(8)O(2), is composed of one 4-hy-droxy-benzamide mol-ecule and half of a 1,4-dioxane mol-ecule. The complete dioxin molecule is generated by crystallographic inversion symmetry. The crystal has an extensive system of hydrogen bonds, in which the three donor H atoms are fully utilized: these result in amide-amide homodimers, and N-...
INTRODUCTION Gemcitabine is a pyrimidine nucleoside analog that becomes triphosphorylated and in this form it competitively inhibits cytidine incorporation into DNA strands. Diphosphorylated gemcitabine irreversibly inhibits ribonucleotide reductase thereby preventing deoxyribonucleotide synthesis. Functioning as a potent chemotherapeutic, gemcitabine decreases neoplastic cell proliferation and...
The present study was aimed at describing the distribution of neuropeptide Y (NPY)-like immunoreactivity in the sixth lumbar (L6) and first sacral segments (S1) of the rat spinal cord, comparing this distribution to that of FMRF-amide-like immunoreactivity and determining whether NPY- and FMRF-amide-like immunoreactivities are present in the same neurons in the dorsal gray commissure (DGC) in L...
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