This study investigates the mechanism of photosensitization and the recombination of excited electron-hole pairs affected by depositing platinum (Pt) on the surface of titanium dioxide (TiO2). A new catalyst of Pt-TiO2 was prepared by a photoreduction process. Being model reactions, the photocatalytic oxidation of methylene blue (MB) and methyl orange (MO) in aqueous solutions using the Pt-TiO2...

A novel self-powered ultraviolet (UV) photodetector was successfully constructed through combining Pt-modified TiO2 nanotubes and Prussian blue (PB)-modified ITO, in which the existence of UV could be judged easily by naked eye with the aid of PB for electrochromic display. More importantly, it could also self-recover without UV light illumination.

The photocatalytic degradation of Acid Red 91 (AR91) and Acid Yellow 23 (AY23) with different molecular structures and different substitute groups using Pt modified TiO2 (PtTiO2 ) nanoparticles was investigated in the presence of visible light irradiation. Pt-TiO2 nanoparticles were prepared with photodiposition method (PD) and characterized by X-ray diffraction (XRD), scanning electron microgr...

We describe the fabrication of a nanometer-size electrode based on an insulating TiO2 film and a metal nanoparticle (NP). The TiO2 film is deposited on the conducting Pt surface of an ultramicroelectrode (UME) to block electron transfer (ET) to solution species. The film thickness is, however, thin enough to enable tunneling to Pt NPs; thus, the subsequent contact of metal NP to the TiO2 film r...

Na promoted Pt/TiO2 catalysts have been studied under high severity, near equilibrium, conditions for use as a single stage WGS catalyst. Addition of 3 wt% Na to a 1 wt% Pt/TiO2 catalyst has been found to improve water gas shift activity significantly compared to Pt/TiO2, Pt/CeO2, and Pt–Re/TiO2 catalysts. This catalyst is stable when the reaction temperature is higher than 250 C. Deactivation ...

Pt@TiO2 core-shell nanostructures were prepared through a hydrothermal method. The dye-sensitization of these Pt@TiO2 core-shell structures allows for a high photocatalytic activity for the generation of hydrogen from proton reduction under visible-light irradiation. When the dyes and TiO2 were co-excited through the combination of two irradiation beams with different wavelengths, a synergic ef...

we explore electro-catalytic properties of a system consisting of platinum and palladium nanoparticles dispersed over a nanotubular self-organized tio2 matrix. these electrodes prepared by electroess and microemulsion of palladium and palladium nanoparticles on to tio2 nanotubes, respectively. titanium oxide nanotubes were fabricated by anodizing titanium foil in ethylene glycol (eg) fluoride-c...

In this study, TiO2 thin film photocatalyst on carbon fibers was used to synthesize ultra-long single crystalline Pt nanowires via a simple photoreduction route (thermally activated photoreduction). It also acted as a co-catalytic material with Pt. Taking advantage of the high-aspect ratio of the Pt nanostructure as well as the excellent catalytic activity of TiO2, this hybrid structure has the...

Black TiO2 was usually obtained via hydrogenation at high pressure and high temperature. Herein, we reported a facile hydrogenation of TiO2 in the presence of a small amount of Pt at relatively low temperature and atmospheric pressure. The hydrogen spillover from Pt to TiO2 accounts well for the greatly enhanced hydrogenation capability. The as-synthesized Pt/TiO2 exhibits remarkably improved p...

This paper reports on the use of nanoporous Pt-TiO2 thin films coated onto magnetoelastic sensors for the detection of ethylene, an important plant growth hormone. Five different metal oxide coatings, TiO2, TiO2+ZrO2, TiO2+TTCN(1,4,7Trithiacyclononane)+Ag, SiO2+Fe, and TiO2+Pt, each having demonstrated photocatalytic activity in response to ethylene, were investigated for their ability to chang...