The first synthesis of bioactive long alkyl chain 5-n-alkylresorcinols, present in whole grain products, by a novel modification of the Wittig reaction is described. All the main long chain 5-n-alkylresorcinols present in rye and wheat, including C(23) and C(25) analogues and haptens, which have not been previously prepared, were synthesised. Microwave-promoted reactions of a semi-stabilized yl...

An efficient method for synthesis of 1Acetal diethyl-1H-indole-3-carbaldehyde by combinaison of 1H-indole-3-carbaldehyde and bromoacetal diethyl using Natural phosphate doped with K2CO3 (NP/K2CO3) is described .The reactions promoted by microwave irradiation are advantageous in many ways because of short reaction time, and solvent free reaction conditions . Several reactions of synthetic import...

BACKGROUND Curcumin and vanillin are the two useful compounds in food and medicine. Bismuth nitrate pentahydrate is an economical and ecofriendly reagent. METHOD Bismuth nitrate pentahydrate impregnated montmorillonite KSF clay and curcumin were subjected to microwave irradiation. RESULTS Microwave-induced bismuth nitrate-promoted synthesis of vanillin from curcumin has been accomplished in...

UNLABELLED BACKGROUND Coumarin derivatives exhibit a wide range of biological properties including promising antioxidant activity. Furthermore, microwave-assisted organic synthesis has delivered rapid routes to N- and O-containing heterocycles, including coumarins and thiazoles. Combining these features, the use of microwave-assisted processes will provide rapid access to a targeted coumarin...