A procedure for the determination of iodide, thiocyanate and perchlorate ions in environmental water by two-dimensional ion chromatography has been developed. At first the iodide, thiocyanate and perchlorate ions were separated from interfering ions by a column (IonPac AS16, 250 mm x 4 mm). The iodide ion, thiocyanate and perchlorate ions were then enriched with an enrichment column (MAC-200, 8...

A simple and rapid way to measure the concentration of iodide in urine with an iodide-selective ion electrode was described. Potentiometric equilibrium was attained in less than 5 min, and a linear calibration curve was obtained over the potassium iodide (KI) concentration range of 10(-2) to 10(-6) M. The coefficients of variation ranged from 6.2 to 10.0% within assay, and 5.4 to 14.4% between ...

A simple, sensitive and rapid method for determination of trace amounts of nitrite ion in real samples is reported. The reaction is initiated by adding known volumes of a nitrite ion solution of identified concentration to acidic solutions of thionine which causes decolorizaiton of reagent with time. The absorbance changes is then monitored spectrophotometrically at l...

In the title compound, [ZnI(2)(C(13)H(19)N(3)O)], the Zn(II) ion is five-coordinated in a distorted square-pyramidal geometry, in which the basal plane is defined by three N atoms from the Schiff base ligand and one iodide ion. A second iodide ligand, situated in the apical position, completes the coordination geometry. In the crystal structure, C-H⋯O hydrogen bonds link a pair of mol-ecules ar...

Poly 8-(3-acetylimino-6-methyl-2,4-dioxopyran)-1-aminonaphthalene (PAMDAN) films were electrodeposited on platinum electrode (Pt), forming PAMDAN/Pt modified electrode, to study its utility in electrooxidation of iodide ion. The electrooxidation process was investigated by cyclic voltammetry. The effects of different factors e.g. scan rate, iodide ion concentration, film thickness and acid conc...

Materials exhibiting high ionic conductivities in the solid state at room temperature have mainly been found in silver ion conductors based on silver iodide and in copper ion conductors which are based on cuprous halide. Silver iodide and cuprous halide show low ionic conductivities at room temperature, while they are high conductivity solids at relatively higher temperatures. In order to obtai...

In a previous paper (1) we reported data, based upon the use of radiosulfur, showing that in the rat the affinity of the whole thyroid for thiocyanate ion is slight but is significantly greater than in other tissues. Baumann and Metzger (2), using different analytical procedures, reported a similar observation. The uptake of thiocyanate ion by the thyroid is of especial interest because of the ...

a simple, sensitive and rapid method for determination of trace amounts of nitrite ion in real samples is reported. the reaction is initiated by adding known volumes of a nitrite ion solution of identified concentration to acidic solutions of thionine which causes decolorizaiton of reagent with time. the absorbance changes is then monitored spectrophotometrically at lmax = 602nm at 25 °c. calib...