Efforts to understand and predict the role of different organic fractions in the fouling of low-pressure membranes are presented. Preliminary experiments with an experimental apparatus that incorporates automatic backwashing and filtration over several days has shown that microfiltration (MF) of the hydrophilic fractions leads to rapid flux decline and the formation of a cake or gel layer, whil...

A "hydrophobic layer in silica" structure was designed to integrate a compact quantum dot (QD) layer with high quantum yield into scalable silica hosts containing desired functionality. This was based on metal affinity driven assembly of hydrophobic QDs with versatile silica substrates and homogeneous encapsulation of organosilica/silica layers.

the produced liquid water in cathode catalyst layer (ccl) has significant effect on the operation of proton exchange membrane fuel cell (pemfc). to investigate this effect, the transport of oxygen in ccl in the presence of immiscible liquid water is studied applying a two-dimensional pore scale model. the ccl was reconstructed as an agglomerated system. to explore the wettability effects, diffe...

objective: adverse surface interactions between one-bottle adhesives and chemical-cured composites may occur with delayed light activation of light-cured composites. the purpose of this study was to assess the effects of delayed activation of light-cured composites on shear bond strength of two one-bottle adhesives with different acidity to bovine dentin. materials and methods: flat dentin surf...

Molecular dynamic simulations were employed to study a waterlike model confined between hydrophobic and hydrophilic plates. The phase behavior of this system is obtained for different distances between the plates and particle-plate potentials. For both hydrophobic and hydrophilic walls, there are the formation of layers. Crystallization occurs at lower temperature at the contact layer than at t...

In the current work, we demonstrate how coordination chemistry can be employed to direct self-assembly based on strong hydrophobic interactions. To investigate the influence of coordination sphere geometry on aqueous self-assembly, we synthesized complexes of the amphiphilic perylene diimide terpyridine ligand with the first-row transition-metal centers (zinc, cobalt, and nickel). In aqueous me...

A quartz crystal microbalance was used for real-time monitoring of fibrinogen cross-linking on three model biomaterial surfaces. Fibrinogen adsorbs slowly and forms a less rigid multi-layer on hydrophobic surfaces, while it adsorbs quickly, forming a single mono-layer on hydrophilic surfaces. The extent of fibrinogen cross-linking is greater on hydrophobic surfaces. Fibrinogen cross-linking can...

We report a solid-state-dye-sensitized solar cell with an efficiency of 4% over the standard air mass 1.5 spectrum s100 mW/cm2d. This was made possible by using an amphiphilic dye with hydrophobic spacers. We dense layer on the TiO2 surface w as anchors and with its hydrophobic isolating chains as blocking layer between hole conductor and TiO2. In addition we studied the dependence of the thick...

Paper-based microfluidic devices are emerging as a new technology for simple, low-cost, portable, and disposable diagnostic and monitoring platform. This article presents a novel method for fabricating microfluidic devices on paper by means of octadecyltrichlorosilane self-assembling and UV/O3-patterning. The hydrophilic filter paper was uniformly coated with a hydrophobic layer of octadecyltri...