The protective performance of zeolite coating on AZ91D magnesium alloy was evaluated using potentiodynamic polarisation and electrochemical impedance spectroscopy (EIS) in 0.1 M sodium chloride solution (NaCl). Electrical equivalent circuit (EEC) was developed based upon hypothetical corrosion mechanisms and simulated to correspond to the experimental data. The morphology and the chemical natur...

--The inhibition of the corrosion of mild steel in hydrochloric acid solutions by the extract of Artemisia Herba-Alba has been studied using gravimetric and electrochemical measurement. Inhibition was found to increase with increasing concentration of the inhibitor. Values of inhibition efficiency calculated from weight loss and potentiodynamic polarization are in good agreement. This value goe...

The electrochemical behavior and the corrosion rate of aluminum electrode have been evaluated in different pH solutions in absence and presence of aggressive anion, using open-circuit potential measurements and potentiodynamic polarization technique. Also, the corrosion inhibiting effects of ortho, meta and para toludine in a solution of pH4 containing 0.1M sodium chloride was investigated usin...

The stability of an electrodeposited nanocrystalline Ni-based alloy coating in a H₂S/CO₂ environment was investigated by electrochemical measurements, weight loss method, and surface characterization. The results showed that both the cathodic and anodic processes of the Ni-based alloy coating were simultaneously suppressed, displaying a dramatic decrease of the corrosion current density. The co...

Corrosion behavior of Ni20Cr coatings deposited by HVOF (high velocity oxygen-fuel) process was evaluated in ZnCl2-KCl (1 : 1 mole ratio) molten salts. Electrochemical techniques employed were potentiodynamic polarization curves, open circuit potential, and linear polarization resistance (LPR) measurements. Experimental conditions included static air and temperatures of 350, 400, and 450°C. 304...

In Sweden, high level radioactive waste will be disposed of in a canister with a copper outer and a cast iron or carbon steel inner. If the iron insert comes into contact with anoxic geological water, anaerobic corrosion leading to the generation of hydrogen will occur. This paper presents a study of the anaerobic corrosion of carbon steel and cast iron in artificial Swedish granitic groundwate...

The purpose of this study is to understand the electrochemical corrosion behavior of 1wt% Cu content Al-6Si-0.5Mg alloy in 0.1M NaCl solution. The potentiodynamic polarization curves reveal that 1wt% Cu content alloy is less prone to corrosion than the Cu free alloy. The EIS test results show that corrosion resistance or polarization resistance (Rct) increases with the addition of 1wt% Cu to Al...

A new experimental method was applied in in situ corrosion monitoring of mild steel Q235 under alternate wet-dry conditions. The thickness of the electrolyte film during the wet cycle was monitored by a high-precision balance with a sensibility of 0.1 mg. At the same time, an electrochemical impedance technique was employed to study the effect of film thickness on corrosion rates. Experimental ...

Pre-plated leadframes packages with a new noble metal finish type were exposed to various electrochemical migration tests, and mixed flowing gas environments to assess the quality and reliability due to these environmental conditions. Packages were tested as discrete parts and also as parts mounted onto printed circuit boards to assess the effect of reflow soldering. Selected packages with SnPb...

A mechanistic model of uniform carbon dioxide (CO2) corrosion is presented that covers the following: electrochemical reactions at the steel surface, diffusion of species between the metal surface and the bulk including diffusion through porous surface films, migration due to establishment of potential gradients, and homogenous chemical reactions including precipitation of surface films. The mo...