Scaling relationships are identified between NMR longitudinal relaxation times and clay dispersion quality in polymer-paramagnetic clay nanocomposites. Derived from a previously published analytical relationship developed from a lamella-based model, the scaling relationships are based on the enhancement of NMR relaxation rates with increasing exfoliation and dispersion homogeneity. The paramagn...

To address the high salinity of flow-back water during hydraulic fracturing, we have studied the equilibrium partitioning of NaCl and water between the bulk phase and clay pores. In shale rocks, such a partitioning can occur between fractures with a bulk-like phase and clay pores. We use an advanced Grand Canonical Monte Carlo (GCMC) technique based on fractional exchanges of dissolved ions and...

Consolidation properties of soil are essential for prediction of the deformation characteristics, determination of which involves considerable time, cost, and rigorous testing process. Further, natural state of saturation is not simulated and thus for partially saturated soils the standard odometer test gives misleading results of the evaluated consolidation parameters particularly the overcons...

Using experiments, theory and simulations, we show that the arrested state observed in a colloidal clay at high concentrations is stabilized by screened Coulomb repulsion (Wigner glass). Dilution experiments allow us to distinguish this disconnected state, which melts upon addition of water, from a low-concentration gel state, which does not melt. Theoretical modeling and simulations at high co...

This study deals with a methodical identification and evaluation of physical-mechanical properties of one genetic type of geological structure. This is represented by an engineering-geological zone of eolian sediments, which is regionally rather abundant. The paper contributes to a need to identify typical soil properties for widespread geological environments in a particular region and thus ad...

The theological parameters of a clay suspension can be used to evaluate particle-particle interactions. Although there have been many studies of the rheological behavior of suspensions of reference clays, only few studies were performed with suspensions of mixed clays, and the rheological properties of these suspensions are not yet fully understood. The length-to-width ratio of some soil clays ...

S-, a male child, four clays' old, was brought from a village to the Colvin Hospital, Allahabad, at about 6 o'clock on the evening of the 31st March, 1884. The hospital dhai came to me and reported that a baby had arrived in whom the natural passage of defecation was absent. I immediately went over to the hospital and saw it. The face was pinched ; the baby could cry only faintly, the breathing...

In order to make virtual modeling as easy as real clay manipulation, we describe a realtime virtual clay model, specially designed for direct hand manipulation. We build on a previous layered model for clay, extending it to handle local properties such as colour or fluidity, to deal with an arbitrary number of tools, and to capture twist effects due to rotating tools. The resulting clay model i...