Most of the optical sensors based on surface plasmon resonance (SPR) are imitated from two main configurations. Firstly, in the KretschmannRaether configuration, a thin metal layer is sandwiched between the prism and the air. Otherwise, the Otto configuration, there is a gap between the metal and the prism. However, the Kretschmann-Raether geometry is more conventional scheme to generate the su...

The metal-ligand, M-L, bonding situation in cyclic trinuclear complexes, CTCs, of copper(I), silver(I), and gold(I) was investigated in terms of the energy decomposition analysis (EDA-NOCV) and natural bond orbitals (NBOs). The anisotropy of the induced current density (ACID) and magnetic response were employed to evaluate the effect of electronic conjugation and metal-metal interactions in CTC...

The surfaces of all metals (except for gold) in air are covered with oxide films. When such a metal is immersed in an aqueous solution, the oxide film tends to dissolve. If the solution is acidic, the oxide film may dissolve completely leaving a bare metal surface, which is said to be in the active state. In near-neutral solutions, the solubility of the oxide will be much lower than in acid sol...

Azide ion is an excellent vibrational probe for studying ion-ion and ion-dipole interactions in solutions because its frequency is sensitively dependent on its local environments. When azide ion forms contact ion pairs with cations in dimethylsulfoxide (DMSO), free azide ion and contact ion pairs are spectrally well distinguished in FTIR spectra. Here, we investigated vibrational population rel...

Introduction: Many of the petrologic characteristics of ureilites that are difficult to reconcile with normal igneous processes [1] can be explained by a smelting model, in which silicate mg (molar Mg/[Mg+Fe]) are controlled by carbon redox reactions [2-4]. However, their metal and siderophile element abundances appear to be inconsistent with such a model [5-7]. The smelting reaction (FeO + C →...

The surfaces of all metals (except for gold) in air are covered with oxide films. When such a metal is immersed in an aqueous solution, the oxide film tends to dissolve. If the solution is acidic, the oxide film may dissolve completely leaving a bare metal surface, which is said to be in the active state. In near-neutral solutions, the solubility of the oxide will be much lower than in acid sol...

In this paper, a theoretical study is conducted in order to establish the feasibility of a liquid metal acoustic resonator ͑liquid gallium or liquid aluminum͒ for high-amplitude acoustic oscillations. The fundamental resonant frequency typically lies between 5 and 40 kHz. The oscillations are induced by an alternating Lorentz force density applied directly to the liquid metal volume. Depending on...

The present study aims at investigating stress and deformation behavior of rotating thick truncated conical shells subjected to variable internal pressure. Material prpperties of the shells are graded along the axial direction by Mori-tanaka scheme, which is achieved by elemental gradation of the properties.Governing equations are derived using principle of stsionary total potential (PSTP) and ...