Ammonia (NH3) as an important precursor to form atmospheric fine particles and secondary inorganic aerosols, should be strictly controlled. Photocatalysis has provided a facile effective way eliminate NH3 pollution under mild conditions, whereas the undesirable products, such NO, NO2 would generated during reaction mechanism remains unclear. In this study, F or Pt modified TiO2 were explored re...

Metallic nanohole arrays exciting both surface plasmon polariton (SPP) and localized resonance (LSPR) in a single thin film have sparked considerable interest the field of plasmonics. To exert their full potential for generation hot electrons visible light, we bury an Au array (AuNHA) under TiO2 layer decorate Pt nanoparticles randomly on to form Pt/TiO2/AuNHA nanocomposite. As compared Pt/TiO2...

The use of coumarin dyes adsorbed on titanium dioxide (TiO2, P25) successfully extended the photocatalytic UV response of TiO2 toward visible light region. The hydrogenation of acetophenone (AP) using TiO2 modified with coumarin dyes proceeded with good chemical efficiencies under visible light irradiation. The role of sacrificial reagents on this dye-sensitized system is also reported.

Au nanoparticles supported on reducible metal oxide surfaces are known to be active catalysts for a number of reactions including CO oxidation and hydrogen production. The exact choice of a metal oxide support has been shown to have a marked impact on activity, suggesting that interactions between Au and the support play a key role in catalysis. For TiO2, a model substrate for Au catalysis, it ...

Titanium dioxide (TiO2) nanoparticles surface-modified by octadecyltrimethoxysilane (commercial name WD-11) are prepared via in situ surface-modification in dehydrated ethanol at room temperature. As-obtained TiO2 nanoparticles are characterized by means of Fourier transform infrared spectrometry, thermogravimetric, X-ray diffraction and transmission electron microscope. The tribological proper...

A 3D Pt/TiO2 architecture assembled from 1D nanowires has been designed and successfully prepared by an environmentally-friendly one-pot solvothermal process. The formation mechanism has been investigated and the unique architecture exhibits an excellent photocatalytic hydrogen production rate as high as 13.33 mmol h(-1) g(-1), the corresponding apparent quantum efficiency reaches 34%.

Heterostructured powders composed of microcrystalline (mc-) BaTiO3 and SrTiO3 cores coated with nanostructured (ns-) TiO2 shells were prepared using a solegel method. The influences of annealing temperature, coating thickness, cocatalyst loading, and core size on photocatalytic hydrogen production were experimentally determined. The amount of hydrogen produced depends on the annealing temperatu...

Despite the rising technological interest in the use of calcium-modified TiO2 surfaces in biomedical implants, the Ca/TiO2 interface has not been studied in an aqueous environment. This investigation is the first report on the use of in situ scanning tunneling microscopy (STM) to study calcium-modified rutile TiO2(110) surfaces immersed in high purity water. The TiO2 surface was prepared under ...

The high-k dielectric TiO2/ZrO2 bilayer composite film was prepared on a Si substrate by radio frequency magnetron sputtering and post annealing in N2 at various temperatures in the range of 573 K to 973 K. Transmission electron microscopy observation revealed that the bilayer film fully mixed together and had good interfacial property at 773 K. Metal-oxide-semiconductor capacitors with high-k ...