In the present work, we report preparation of NiO nanoparticles with well-defined plate morphology by solid-state reaction of NiCl2∙6H2O and the Schiff base ligand N,N′-bis-(3-methoxysalicylidene)benzene-1,4-diamine), as a novel precursor via solid state thermal decomposition method. This method is a simple and environmentally friendly for preparing t...

Recently the synthesis of ultrafine powders has drawn considerable attention because these powders can have physical and chemical properties superior to those of bulk specimens. In particular, emphasis is on the preparation of ultrafine ceramic powders for their applications in the development of sintered products having higher density and lower sintering temperature. One such industrially impo...

A novel class of high-entropy pyrochlore compounds with multiple elements at the and B site positions (A2B2O7) was successfully obtained. Powders (La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 nominal composition were fabricated from pure metal oxides obtained through a reaction nitrates (for A) chlorides B) sodium hydroxide during solid-state displacement (SSDR). The phase evolution...

Ceramic samples of polycomponent solid solution (Y0.96Eu0.01Sm0.01Tb0.01Er0.01)Nb0.7Ta0.3O4 have been prepared by sol–gel synthesis from fine powders obtained using nitrate solutions rare earth elements REE and coprecipitated hydroxides niobium tantalum. The structural state the initial powders’ crystal lattice has investigated. morphological features microstructure ceramics studied in dependen...

Nanostructures of magnesium oxide is one of the most attractive materials which have shown various applications in many aspects of industries. So, finding a controllable and inexpensive technique to produce desirable nanostructures of MgO is valuable. In this work, magnesium oxide (MgO) with different morphologies was successfully prepared via a simple solid-state method. The molar ratio of sod...

In this paper, we have focused on the preparation and characterization of copper oxide nanoparticles by solid state thermal decomposition of copper(I) iodide in the presence of thiosemicarbazone ligands without the need for a catalyst, employing toxic solvent, template or surfactant and complicated equipment, which makes it efficient, one-step, simple and environment-friendly. CuO nanoparticles...

caco3 nanoparticles have been synthesized via heat-treatment of a new precursor and solid state reaction. effect of calcinations temperature and quantity of surfactant on particle size has been investigated. the products were characterized by x-ray diffraction (xrd), scanning electron microscopy (sem), transmission electron microscopy (tem) and fourier transform infrared (ft–ir) spectroscopy.

We describe a new compact acousto-optically Q-switched diode-pumped solid-state (DPSS) intracavity frequency-tripled neodymium-doped yttrium vanadate laser capable of producing ~100 mW of 213 nm power quasi-continuous wave as 15 ns pulses at a 30 kHz repetition rate. We use this new laser in a prototype of a deep ultraviolet (UV) Raman standoff spectrometer. We use a novel high-throughput, high...

The importance of solid-state diffusion and crystal growth of the solid product in a gas-solid reaction with solid product formation (GSRSPF) are discussed with direct sulfation of limestone as a representative example. A GSRSPF usually involves nucleation and crystal growth of the solid product, which are necessary processes for the formation of the new phase of the solid product. Solid-state ...