During the processing of laminar ceramic, biaxial, residual stresses can arise due to differential thermal contraction between unlike layers. A tensile stress can cause pre-existing flaws to extend across the layer and into the adjacent layers and then tunnel until they meet either another crack or a free surface. A previous analysis has shown that for a given residual stress there is a critica...

Local atomic structures of Zr and dopant cations in zirconia solid solutions with Fe,03, Ga203, Y203, and Gd203 .have been determined. The Zr ions in both partially stabilized tetragonal and fully stabilized cubic zirconia have their own characteristic structures which are dopant-independent. The dopant cations substitute for Zr ions despite severe local distortions necessitated by the large di...

The aim of this randomized controlled clinical trial was to compare the early clinical outcome of slip-cast glass-infiltrated Alumina/Zirconia and CAD/CAM Zirconia all-ceramic crowns. A total of 30 InCeram Zirconia and Cercon Zirconia crowns were fabricated and cemented with a glass ionomer cement in 20 patients. At baseline, 6-month, 1-year, and 2-year recall appointments, Californian Dental A...

Abstract This work focuses on improving the durability of Ni/yttria-stabilized zirconia (YSZ) fuel electrode-supported solid oxide cells under reversible operation mode by infiltrating nano-sized electrocatalysts into both electrodes. The resulting cell consists a CGO (Gd-doped CeO 2 ) scaffold-based oxygen electrode that is infiltrated with LSC (La 0.6 Sr 0.4 CoO 3-δ and CGPO (Gd, Pr-co-doped ...

Iron-manganese-doped sulfated zirconia nanoparticles with both Lewis and Brønsted acidic sites were prepared by a hydrothermal impregnation method followed by calcination at 650°C for 5 hours, and their cytotoxicity properties against cancer cell lines were determined. The characterization was carried out using X-ray diffraction, thermogravimetric analysis, Fourier transform infrared spectrosco...

Nanorods of a three-dimensional Zn(II) metal-organic framework, [Zn₂(btec)(DMF)₂]n (1) (btec=1,2,4,5-benzenetetracarboxylate, DMF=N,N-dimethylformamide), have been synthesized by a sonochemical process and characterized by field emission scanning electron microscopy (FE-SEM), powder XRD and FT-IR spectroscopy. Structural determination of compound 1 was determined by single crystal X-ray diffrac...

Zirconia has been recently introduced in prosthetic dentistry for the fabrication of crowns and fixed partial dentures, in combination with CAD/CAM techniques. Zirconia stabilized with Y2O3 has the best properties for these applications. This project aims at producing cast Zirconia blocks primarily for dental application that is more cost effective and biocompatible in comparison to the commerc...

An yttria stabilised zirconia which exhibits a coreshell microstructure was investigated as a method to produce a zirconia with high ionic conductivity and improved thermal shock resistance. Zirconia grains consist of an outer shell of tetragonal zirconia with an inner core of monoclinic phase zirconia. Impedance spectroscopy was used to identify the e€ect of processing conditions on the grain ...