We describe a simple way to create patterns of ‘‘soft’’ biomolecular nanostructures such as vesicles on ‘‘hard’’ surfaces such as gold. The key to our approach is the use of an amphiphilic biopolymer as an ‘‘interconnect’’ or tether. The polymer is hydrophobically modified chitosan (hm-chitosan), which is obtained by covalently attaching alkyl tails to the backbone of chitosan. We electrodeposi...

4-META/MMA-TBB resin has clinically favorable mechanical and bonding properties and undergoes unique, moisture-insensitive polymerization. To explore the potential usefulness of 4-META/ MMA-TBB resin as a pulp capping material, this study examined its biological and biochemical properties. Rat dental pulp cells were cultured on 4-META/MMA-TBB resin, resin-modified glassionomer (RMGI) cement, an...

OBJECTIVE TiO(2) nanoparticles treated with the organosilane allyltriethoxysilane (ATES) are used to improve the mechanical properties of dental resin-based composites (RBCs, Z100, 3M ESPE). METHODS TiO(2) nanoparticles were sonically dispersed in an ethanol solution containing ATES. The modified particles were washed in pure ethanol and dried before being used as filler. Fourier transform in...

A resin monomer-soluble polyrotaxane (PRX) crosslinker with cleavable end groups was synthesized to develop degradable photosetting composite resins. The PRX containing 50 α-cyclodextrins (α-CDs) with disulfide end groups was initially modified with n-butylamine to obtain a resin monomer-soluble PRX. The PRX containing 13 n-butyl groups per α-CD molecule was completely soluble in conventional r...

BACKGROUND Chitosan is a functional biopolymer that has been widely used as a hemostat. Recently, its efficacy has been questioned due to clinical failures as a result of poor adhesiveness. The purpose of this study was to compare, in a severe groin injury model in swine, the hemostatic properties of an unmodified standard chitosan sponge with standard gauze dressing and a novel hydrophobically...

A new modified magnetic Graphene Oxide with Chitosan and Cysteine wassynthesized for removing Pb2+ ions from aqueous solution. The properties of thisadsorbent were characterized by Field Emission Scanning Electron Microscopy (FESEM),Vibrating Sample Magnetometer (VSM) and Energy Dispersive Analysis Systemof X-ray (EDAX). Physicochemical parameters such as effect of pH, c...

The glucose oxidase (GOx) enzyme was immobilized on chitosan-based porous composite membranes using a covalent bond between GOx and the chitosan membrane. The chitosan-based porous membranes were prepared by the combination of the evaporation- and non-solvent-induced phase separation methods. To increase the membrane conductivity, carbon nanotubes (CNTs) were added to the chitosan solution. The...

The removal of Pb(II) from aqueous solutions by using modified Amberlite XAD-7HP resin has been studied. The resins have been prepared by complete mixing of Amberlite XAD-7HP resin with anionic surfactant-dioctyl sodium sulphosuccinate (DOSSS) and EDTA-disodium salt (Chelating agent) in an aqueous solution. SEM studies revealed the morphological observations of the unloaded adsorbent and thereb...