Conventional supported metal catalysts are metal nanoparticles deposited on high surface area oxide supports with a poorly defined metal-support interface. Typically, the traditionally prepared Pt/ceria catalyzes both methanation (H2/CO to CH4) and water-gas shift (CO/H2O to CO2/H2) reactions. By using simple nanochemistry techniques, we show for the first time that Pt or PtAu metal can be crea...

The chemical equilibria concerning formic acid are computationally investigated in water over a wide range of thermodynamic conditions. The solvation free energies for relevant C1 compounds are evaluated in the method of energy representation, and are used to assess the solvent effect on the formic acid reactions. In the two competitive decomposition processes of formic acid, the solvent strong...

Metrology in atomic physics has been crucial for a number of advanced determinations of fundamental constants. In addition to very precise frequency measurements, the molar polarizability of an atomic gas has recently also been measured very accurately. Part of the motivation for the measurements is due to ongoing efforts to redefine the International System of Units (SI), for which an accurate...

Landfill Gas to Energy This research investigates the utilization of landfill gas, an abundant waste product, by reforming it to syngas that can be converted to liquid fuels using Fischer Tropsch or to a H2 rich stream using water-gas shift. 65% of the 413 million tons of municipal solid waste (MSW) generated per year in the United States is landfilled, and 67% of the landfilled MSW is composed...

A CO2 laser dispersion interferometer (DI) has been developed for both magnetically fusion plasmas and atmospheric pressure plasmas. The DI measures the phase shift caused by dispersion in a medium. Therefore, it is insensitive to mechanical vibrations and changes in the neutral gas density, which degrade the resolution of the plasma measurement. We installed the DI on the Large Helical Device ...

We propose a new approach for calculating the change of the absorption spectrum of a molecule when moved from the gas phase to a crystalline morphology. The so-called gas-to-crystal shift Δ[Formula: see text] m is mainly caused by dispersion effects and depends sensitively on the molecule's specific position in the nanoscopic setting. Using an extended dipole approximation, we are able to divid...

Na promoted Pt/TiO2 catalysts have been studied under high severity, near equilibrium, conditions for use as a single stage WGS catalyst. Addition of 3 wt% Na to a 1 wt% Pt/TiO2 catalyst has been found to improve water gas shift activity significantly compared to Pt/TiO2, Pt/CeO2, and Pt–Re/TiO2 catalysts. This catalyst is stable when the reaction temperature is higher than 250 C. Deactivation ...

increased alveolar pressure in the fluid-filled lung. 1 0 However, in our patient, the shift was noted at a time when the lung was not filled with fluid. It appears likely that the perfusion shift we observed was a response to regional alveolar hypoxia, related to the postiavage decrement in ventilation. 1 3 ' 1 4 Sequential ventilation-perfusion scintiphotographic studies also were useful in d...