a novel, simple, sensitive and effective method has been developed for preconcentration of hg(ii) on nano-fe3o4-dop-ed solid-phase extraction adsorbent. in this paper, dioctyl phthalate (dop) was used to encapsulate nano-fe3o4 and produce a nano-fe3o4-dop sorbent based new sorbent was prepared. this was treated with ethylenediamine (ed) in another solvent-free procedure for the formation of a n...

When mechanically induced progressive failure of rock and the associated changes in hydro fracturing process, it is difficult to track the dynamic evolution of fractures beneath the earth. To overcome this, recent developments in hydro-fracturing technique have tended to follow hybrid approaches. An attempt was made to develop an empirical relationship to predict the Fracture length in millimet...

Electron beam butt welding of stainless steel (SS 304) and electrolytically tough pitched (ETP) copper plates was carried out according to central composite design of experiments. Three input parameters, namely accelerating voltage, beam current and weld speed were considered in the butt welding experiments of dissimilar metals. The weld-bead parameters, such as bead width and depth of penetrat...

The preformulation of insoluble drugs, sulfadiazine and aluminium hydroxyde, were studied in order to achieve a suspension with desirable requirements. The objective of the formulator is to avoid the irreversible aggregation called “caking”, and to obtain a suspension with an airy, large volume sediment easily redispersible and with suitable rheological properties. An experimental design useful...

The synthesis of structured lipids with nutraceutical applications, such as medium-long-medium (MLM) triacylglycerols, via modification oils and fats represents a challenge for the food industry. This study aimed to synthesize MLM-type dietary triacylglycerols by enzymatic acidolysis cottonseed oil capric acid (C10) catalyzed Lipozyme RM IM (lipase from Rhizomucor miehei) in fluidized bed react...

Enzymatic synthesis of short-chain esters (flavours) might enable their labelling as natural, increasing value. Covalently immobilised Rhizopus oryzae lipase (EO-proROL) was used to synthesise isoamyl butyrate and acetate. In cyclohexane, the best performer reaction solvent, 1.8 times higher yield (ca. 100%) than acetate 55%) obtained. Optimum initial acid concentration (410 mM) acid:alcohol mo...

The purpose of this study was the investigation of the removal of phenol with nanoparticles zero valent iron and iron powder. The effect of various parameters such as initial concentration, pH, contact time, and dosage of NZVI and Fe powder was examined, and a Central Composite Design (CCD) was then applied to appraisal the effect of these variables. The chemical and physical characteristic...