5-((4-alkoxyphenyl)azo)salicyladehyde, 5-((4-alkoxyphenyl)azo)-n-(npentyl, ndodecyl)-salicyladimine and bis [5-((4-alkoxyphenyl)azo)-n-(npentyl, ndodecyl)-salicyladiminato]copper(ii) [alkoxy=oncnh2n+1; n=3-7] homologues were synthesized and characterized by elemental analyses, mass and ir spectra. all complex homologues are thermally stable. cyclic voltammetric studies indicated that all copper...

Direct luminescence (DL) spectra of 4H Cd12 in the spectral region 1.8-3.4 eV at temperatures between 9.3 and 215 K and thermally stimulated luminescence (TSL) spectra are reported. The DL spectra consist of several overlapping broad emission bands. These bands are due to radiative recombination of localized (trapped) electrons with localized (trapped) holes. With a simple theory, which takes i...

Thermally stimulated relaxation (TSR), employing thermally stimulated luminescence (TSL) and thermally stimulated conductivity (TSC) as experimental techniques, in Polyacrylamide (PAA) have been studied; in the temperature range 300 480 K. Measurements of electrical conductivity () at various temperatures, in the same temperature range have been made, in both as-grown and UV-irradiated PAA fil...

The response of thermally stimulated luminescence (TSL) is investigated theoretically. An original dimensionless treatment is proposed, first to highlight the key dimensionless factors rationalizing the competition between the mechanisms at play during the TSL readout, and second to clean up the approach from any particular values of the relevant physical parameters. The approach holds for an u...

INTRODUCTION The Fairchild Power33 uses a flat leaded package to achieve SO-8 type performance in a form factor that is 70% smaller. This packaging technology has been increasingly used for power related products due to its low package height, and excellent thermal performance for size. This is largely due to the large thermal pad in the center of the package which solder directly to the printe...

We report first principles ab initio density functional calculations of hydrogen dynamics in hydrogenated amorphous silicon. Thermal motion of the host Si atoms drives H diffusion, as we demonstrate by direct simulation and explain with simple models. Si-Si bond centers and Si ring centers are local energy minima as expected. We also describe a new mechanism for breaking Si-H bonds to release f...

In shape memory alloys the Thermoelastic Martensitic Transformation (TMT), intrinsically stepwise, can be either thermally induced or stress-induced. Moreover, it has already been shown that an extrinsic fragmentation of thermally induced transformation can be stimulated ("Step-wise Martensite to Austenite Reversible Transformation", SMART) by means of Incomplete Cycles on Heating (ICHs): the S...

In the present work, electron paramagnetic resonance (EPR) spectra and thermoluminescence (TL) emission of colourless natural topaz from Santo Antônio do Jacinto, Brazil, was studied as a function of thermal treatment and gamma irradiation dose, focussing on the use of this material as a radiation dosimeter. EPR measurements on "as-received" samples at room temperature provided signals in the r...

Organic light-emitting diodes (OLEDs) under constant current operation suffer from a decrease of luminance accompanied by an increase of driving voltage. We report a way to greatly improve the stability of OLEDs having a green emitter exhibiting thermally activated delayed fluorescence (TADF), (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl) isophthalonitrile (4CzIPN), by introducing ultrathin (1 to 3 n...