A T-jump/time-of-flight mass spectrometer (T-Jump/TOFMS) is used to probe the decomposition of several aminotetrazole containing energetic materials under very high heating rates of 10(5)-10(6) K/s. The materials investigated are 5-amino-1-methyl-1H-tetrazolium dinitramide (MeHAT_DN), 1,5-diamino-4-methyl-1H-tetrazolium dinitramide (MeDAT_DN), 1,5-diamino-1H-tetrazolium nitrate (DAT_N), 1,5-dia...

A semisolid tetrazolium salt agar medium developed for testing sensitivity to KCN is easier to interpret, has a longer storage life, and is less critical in the size of inoculum than is Moeller KCN broth medium.

The main aim of this study was to compare selected nonspecific immunity parameters in 14 allergic and 12 healthy horses. Each animal was assessed according to the following parameters: in vitro functional capacity of phagocytic cells using the nitro blue tetrazolium chloride reduction test, both spontaneous (NBT) and zymozan stimulated (NBTs), and ingestion capacity of phagocytic cells using a ...

Early recognition of the presence of Shigella in the stool of a patient facilitates use of the most specific therapy and proper consideration of epidemiologic implications. The positive diagnosis of a Shigella infection requiies isolation of the etiologic agent from the stool of the patient and its identification by biochemical and serological studies which usually require a minimum of 36 to 48...

A measured area of blotting paper was used as a vehicle for transferring a constant aliquot of urine on to the surface of a culture medium. The number of bacterial colonies growing in the inoculum area of the medium corresponded to the number of organisms in the urine. One thousand, two hundred and seventy-five urines from women attending an ante-natal clinic were tested by this method, and the...

An efficient "one-pot" approach to multiple substituted ureas from N-arylcyanamide and diaryliodonium salts has been presented. The two-step procedure involved the weak base-promoted chemoselective arylation of secondary amines with diaryliodonium and Cu-catalyzed nucleophilic addition of N-arylcyanamide with second diaryliodonium. The diverse unsymmetrical arylureas were obtained in up to 91% ...

A series of chiral triazolium salts have been synthesized from methyl l-phenylalaninate hydrochloride. The NHCs derived from this class of novel triazolium salts were found to be highly efficient catalysts in the annulation reaction of enals and 2-naphthols. These reactions proceeded with high chemoselectivity and wide substrate scope affording enantioenriched β-arylsplitomicins in good yields ...

Polysubstituted pyridinium salts are valuable pharmacophores found in many biologically active molecules. Their synthesis typically involves the use of multistep procedures or harsh reaction conditions. Here, we report water-based phosphate mediated reaction conditions that promote the condensation of arylacetaldehydes with amines to give 1,3,5-pyridinium salts. The reaction, carried out at pH ...