In the present study we tested the hypothesis that phosphorylation of the 20,000-dalton light chain subunit of smooth muscle myosin (LC20) by the calcium-activated and phospholipid-dependent protein kinase C regulates contraction of chemically-permeabilized (glycerinated) porcine carotid artery smooth muscle. Purified protein kinase C and oleic acid were used to phosphorylate LC20 in glycerinat...

Replacing liquid electrolytes with solid-state conductors is one of the key challenges to increasing safety and energy density next-generation Li secondary batteries. In this work, NASICON-type Li1+xAlxZryTi2?x?y(PO4)3 0 ? x, y 0.2 solid were synthesized using sol-gel techniques at various sintering temperatures (800, 900, 1000 °C). Their morphology conducting properties studied determine optim...

A new iron phosphate, disodium calcium manganese(II) iron(III) tris(phosphate), Na2CaMnFe(PO4)3, has been synthesized as single crystals by the flux technique. This compound crystallizes in the monoclinic space group C2/c. The structure belongs to the alluaudite structural type and thus, it obeys the X(2)X(1)M(1)M(2)2(PO4)3 general formula. Both the X(2) and X(1) sites are fully occupied by sod...

The crystal of hydroxyapatite, Ca10 (PO4) 6 (OH) 2 has a characteristic that it varies easily depending on the acidic base environment around the enamel. The etymology of apatite is said to come from the Greek word meaning “to deceive” since it contains various elements in the Ca, PO4, and OH areas and changes appearance. In other words, the true character behind the demineralization and remine...

Low molecular water-soluble chitosan was prepared by the depolymerization of chitosan in the presence of a series of catalysts with active W(O2) sites. Both the peroxo species [W2O3(O2)4]2- and {PO4[WO(O2)2]4}3- showed high efficiency in the degradation of chitosan, indicating that the degradation mechanism did not follow the radical mechanism. That means •OH is not the active species, which ha...

The potential for non-point-source pollution of surface waters from agricultural lands continues to be a concern. Our objective was to determine the effect of surface residue management and fertilizer application timing in regards to soil moisture conditions on nutrient losses in runoff. Studies were conducted using a rainfall simulator that applied 125 mm h-1 for 3 h to an Austin (Udorthentic ...

Soil erosion, runoff and related nutrient losses are a big risk for soil fertility in Cabo Verde drylands. In 2012, field trials were conducted in two agro-ecological zones to evaluate the effects of selected techniques of soil-water management combined with organic amendments (T1: compost/manure + soil surfactant; T2: compost/animal or green manure + pigeon-pea hedges + soil surfactant; T3: co...

There is considerable interest in the biogeochemical cycling of cadmium (Cd) and phosphate (PO4) in surface waters, driven in part by the ongoing development of a paleonutrient proxy that utilizes Cd preserved in fossil planktonic foraminifera to determine past PO4 utilization efficiencies in ocean surface waters. The present article reports the results of a field study into the effects of Fe l...

The structure of apatite, Ca10(PO4)6F2, can be described in terms of an approximate hexagonal close packed set of spheres in which each sphere represents a tetrahedral PO4 3ion. This packing has octahedral interstitial sites that form channels through the structure parallel to the hexagonal axis. The F and 4/10ths of the Ca ions are located in these channels forming columns of F and Ca ions res...

A new actinide borate phosphate, U2[BO4][PO4], was synthesized in a Walker-type multianvil apparatus at 12.5 GPa and 1000 °C. The crystal structure was determined from single-crystal X-ray diffraction data collected at room temperature. U2[BO4][PO4] crystallizes in the monoclinic space group P21/c with four formula units per unit cell and the lattice parameters a = 854.6(2), b = 775.3(2), c = 8...