We calculate the shift, due to interatomic interactions, of an optical transition in an atomic Fermi gas trapped in an optical lattice, as in recent experiments of Campbell et al. [Science 324, 360 (2009)]. Using a pseudospin formalism to describe the density matrix of atoms, we derive a Bloch equation which incorporates both spatial inhomogeneity of the probe laser field and interatomic intera...

Contributions to the gas-to-liquid chemical shifts of water arising from the electric field gradient of the surrounding molecules have been calculated as a function of the temperature. Since the theoretical model is based on perturbation theory, this part of the chemical shift may be calculated from quadrupole shielding polarizabilities and statistical mechanical ensemble averages of external e...

Ammonia (NH3) is produced from atmospheric nitrogen and hydrogen from a hydrocarbon source. Natural gas is the most commonly used hydrocarbon feedstock for new plants; other feedstocks that have been used include naphtha, oil, and gasified coal. Natural gas is favored over the other feedstocks from an environmental perspective. Ammonia production from natural gas includes the following processe...

In a typical continuous-flow optical pumping setup, the chemical shift of xenon in the adsorbed phase depends on the gas flow rate due to warming of the sample surface by the gas stream. Calibration of the system using the (207)Pb resonance of solid lead nitrate is necessary to determine the actual sample temperature. Optimum pulse repetition rates are strongly affected by gas flow and spin-lat...

We report experimental results of proton– and electron–beam–induced near–infrared (NIR) fluorescence in high–pressure Xe gas at room temperature. The investigated wavelength band spans the range 0.7 ≤ λ ≤ 1.8μm. In the previously unexplored range for λ > 1.05μm we have detected a broad continuum NIR fluorescence at λ ≈ 1.3μm that shifts towards longer wavelengths as pressure is increased up to ...

In this paper, recent results of plasma processing of natural gas are described. The use of a plasma reformer for the generation of hydrogen rich gas from natural gas has been investigated. In an accompanying paper, progress in plasma reforming of diesel fuel is described. The reformate composition has been investigated as a function of the initial mixture of air and methane. High methane conve...

To control indoor air quality, a novel freon gas sensor of piezoelectric microcantilever coated with zeolite has been developed in this paper. Excited by an ac voltage, the microcantilever is employed to detect the concentration of sample freon-12 gas ranged from 0 to 100 ppm by the effect of the specific MFI zeolite modification. High selectivity and sensitivity combined with excellent repeata...

Hartree-Fock (HF) and Density Functional Theory (DFT) methods employed to study the effect of conformational change on the 13C chemical shifts of 6-mono axial and equatorial substituted and 6,7-di axial-axial, equatorial-equatorial and axial-equatorial substitutedderivatives of 5,6,7,8-tetrahydrodibenzo[a,c]cyclo-octene. The geometry of the conformers have been optimized...

In this research, Quantum-mechanical calculations were performed at the HF method with the 6-31+G*basis set and at the B3LYP method with the 6-31+G* basis set in the gas phase and five solvents such as water, DMSO, methanol, ethanol and dichloromethane at six temperatures. According to these theoretical results of IR, we extracted thermo chemical parameters such as enthalpy (∆H Kcal/mol), Gibbs...