BACKGROUND Fatty alcohols are widely used in industrial chemicals. The biosynthetic pathways for fatty alcohols are diverse and widely existing in nature. They display a high capacity to produce fatty alcohols by the metabolic engineering of different microbe hosts. Direct recycling of carbon dioxide to fatty alcohols can be achieved by introducing a fatty alcohol-producing pathway into photosy...

Temperature programed desorption has been used to study the desorption kinetics and desorption energies of a set of alcohols and fluorinated alcohols adsorbed on an a-CHx film. The alcohols serve as models for the hydroxyl end groups of Fomblin Zdol, the lubricant most commonly used with the amorphous carbon overcoats sputtered onto the surfaces of magnetic data storage disks. Temperature progr...

Characteristic molecular dynamics of reactant molecules confined in the space of the nanometer scale augments the frequency of collisions with the electrified surface so that a given faradaic reaction can be enhanced at nanoporous electrodes, the so-called nano-confinement effect. Since this effect is grounded on diffusion inside nanopores, it is predicted that adsorption onto the surface will ...

This paper reviews the development, design and applications of electrochemical technologies in water and wastewater treatment. Particular focus was given to electrodeposition, electrocoagulation (EC), electroflotation (EF) and electrooxidation. Over 300 related publications were reviewed with 221 cited or analyzed. Electrodeposition is effective in recover heavy metals from wastewater streams. ...

In the exploration of highly efficient direct ethanol fuel cells (DEFCs), how to promote the CO2 selectivity is a key issue which remains to be solved. Some advances have been made, for example, using bimetallic electrocatalysts, Rh has been found to be an efficient additive to platinum to obtain high CO2 selectivity experimentally. In this work, the mechanism of ethanol electrooxidation is inv...

The synergistic effect of WC and Pd has large benefit for ethanol electrooxidation. The small-sized Pd nanoparticles (NPs) decorated tungsten carbide on graphene (Pd-WC/GN) will be a promising anode catalyst for the direct ethanol fuel cells. The density functional theory (DFT) calculations reveal that the strong interaction exists at the interface between Pd and WC, which induces the electron ...

Electroantennograms (EAGs) were recorded from unmated, laboratory-reared, male and female oriental fruit flies, Dacus dorsalis, in response to a range of between C~ and Cl2 carbon chain-length saturated and unaturated aliphatic alcohols and aldehydes, most all of which are known host-plant volatiles. Only two of the 35 compounds tested elicited significantly larger EAGs from female than male an...

Rh nanoneedles and nanorods have been generated with the help of functional molecules like hexamethylene tetraamine and tridecylamine (1:2 in mM scale) as effective capping agents for electrocatalytic studies. A noteworthy negative shift of the onset potential towards the electrooxidation of formic acid compared to that of bulk Rh from cyclic voltammetry along with current densities from curren...

Hypervalent iodine(III)/TEMPO-mediated oxidation of various aliphatic, aromatic and allylic alcohols to their corresponding carbonyl compounds was successfully achieved by using microreactor technology. This method can be used as an alternative for the oxidation of various alcohols achieving excellent yields and selectivities in significantly shortened reaction times.

Liquids composed of small-molecule monohydroxy alcohols are demonstrated to display rheological behavior typical for oligomeric chains. This observation was made possible by rheological experiments in which more than seven decades in frequency and more than five decades on the mechanical modulus scale are covered. The singly hydrogen-bonded monohydroxy alcohols were chosen because they display ...