A perpendicular mesoporous platinum electrode with a flat surface is successfully synthesized by electrodeposition using titania nanopillars as template, and the electrochemical studies indicate that this material is a promising catalytic electrode for fuel cells because of its high surface area and perpendicular nanopores.

The structure of the dye layer adsorbed on the titania substrate in a dye-sensitized solar cell is of fundamental importance for the function of the cell, since it strongly influences the injection of photoelectrons from the excited dye molecules into the titania substrate. The adsorption isotherms of the N719 ruthenium-based dye were determined both with a direct method using the depth profili...

The fatigue properties of ultrathin protective coatings on silicon thin films were investigated. The cohesive and delamination fatigue properties of 22 nm-thick atomic-layered-deposited (ALD) titania were characterized and compared to that of 25 nm-thick alumina. Both coatings were deposited at 200 °C. The fatigue rates are comparable at 30 °C, 50% relative humidity (RH) while they are one orde...

Metal-organic frameworks (MOFs) provide access to structures with nanoscale pores, the size and connectivity of which can be controlled by combining the appropriate metals and linkers. To date, there have been no reports of using MOFs as templates to make porous, crystalline metal oxides. Microporous titania replicas were made from the MOF template HKUST-1 by dehydration, infiltration with tita...

Titanium dioxide (titania) nanoparticle aggregation is an important factor in understanding cytotoxicity. However, the effect of the aggregate size of nanoparticles on cells is unclear. We prepared two sizes of titania aggregate particles and investigated their biological activity by analyzing biomarker expression based on mRNA expression analysis. The aggregate particle sizes of small and larg...

Titanium oxide compounds TiO,Ti2O3, and TiO2 with a considerable extent of nonstoichiometry were fabricated by pulsed laser ablation in water and characterized by X-ray/electron diffraction, X-ray photoelectron spectroscopy and electron energy loss spectroscopy. The titanium oxides were found to occur as nanoparticle aggregates with a predominant 3+ charge and amorphous microtubes when fabricat...

Monodisperse spherical hollow and non hollow titania particles of variable sizes are produced in a sol gel synthesis from Ti(EtO)4 in ethanol. Hollow spherical particles of rutile were obtained by coating colloidal polystyrene beads with a titanium oxide hydrate layer and subsequently calcination at elevated temperatures in ol\ygen atmosphere. The non hollow titania particles were produced in t...

We report on the conformal synthesis of ultrathin films from the amino acid histidine on flat silicon substrates and 3D periodic polymer structures via plasma enhanced chemical vapor deposition. We demonstrate the efficient utilization of this functional amino acid nanocoating for the formation of individual titania nanoparticles with dimensions from 2 to 15 nm depending upon reduction conditio...

We developed a novel fabrication technique of titania microspheres utilizing a robust external gelation method on an oil/hydrogel interface. By putting sodium alginate droplets on an interface between oil and Ca 2+ -loaded hydrogel, surfactant dissolved in oil forms amphiphilic bilayer. Water molecules and calcium ions transfer through this amphiphilic bilayer. As a result, alginate droplets sh...

1.Introduction Titania powder can be applied in a wide range of industries like pigments, catalyst support and photocatalysts because of its interesting optical, dielectric and catalytic properties. Many methods of preparing the nanometer titanium have been put forward. Among these, the chemical methods draw the scientific interesting because of their advantages of low cost and low reaction tem...