Introduction The fuel processor in which hydrocarbon fuels can be converted into hydrogen has recently attracted much attention as a result of the advancement in the fuel cell technology. In a fuel processor, the water-gas shift (WGS) reaction plays a crucial role in the transformation of CO, a well-known poisonous gas to electrode of fuel cell, into hydrogen through reaction with steam. In WGS...

Abatement of trichloroethylene (TCE, 250 ppm in air) was studied in a novel nonthermal plasma (NTP) dielectric barrier discharge reactor with an inner electrode made of sintered metal fibers (SMF). The SMF electrodes modified with TiO2 and MnO2 were observed to be catalytically active. Their efficiency in TCE decomposition was compared with a Cu inner electrode. The SMF electrode modified with ...

In exploration of low-cost electrocatalysts for direct methanol fuel cells (DMFCs), Pt modified tungsten carbide (WC) materials are found to be great potential candidates for decreasing Pt usage whilst exhibiting satisfactory reactivity. In this work, the mechanisms, onset potentials and activity for electrooxidation of methanol were studied on a series of Pt-modified WC catalysts where the bar...

The photocatalytic oxidation of phenol in water in the band reactor with supported TiO2 catalysts was investigated. Modified anatase/Al2O3 catalysts were used as the photocatalysts. The main aim of these studies was to determine catalytic activity of TiO2/Al2O3 and V-TiO2/Al2O3 in the removal of phenol from water. The effectiveness was measured in the configurations: TiO2/UV/O2/H2O2, TiO2/O2/H2...

Two times higher activity and three times higher stability in methanol oxidation reaction, a 0.12 V negative shift of the CO oxidation peak potential, and a 0.07 V positive shift of the oxygen reaction potential compared to Pt nanoparticles on pristine TiO2 support were achieved by tuning the electronic structure of the titanium oxide support of Pt nanoparticle catalysts. This was accomplished ...

Nanotubos de TiO2 (TiO2NTs) foram decorados com nanopartículas de Pt via deposição catódica. Estas nanopartículas foram uniformemente distribuídas, altamente separadas e espaçadas sobre toda a superfície do TiO2NT para o menor tempo de deposição, com os tamanhos das partículas de Pt proporcionais às cargas aplicadas. O fotoeletrodo de Pt/TiO2NTs apresentou intenso pico de absorção na região do ...

The interfacial compatibility between compact TiO2 and perovskite layers is critical for the performance of planar heterojunction perovskite solar cells (PSCs). A compact TiO2 film employed as an electron-transport layer (ETL) was modified using 3-aminopropyl trimethoxy silane (APMS) hydrolysate. The power conversion efficiency (PCE) of PSCs composed of an APMS-hydrolysate-modified TiO2 layer i...

It has been found that the electrocatalytic properties of metallic nanoparticles supported on transition metal oxides are affected by existing strong metal–support interaction (SMSI). Herein, effects SMSI electrocatalysis hydrogen evolution reaction (HER) were investigated in acid electrolyte using Pt and Ag carbon titanium oxide (TiO2). High-resolution transmission electron microscopy (HR–TEM)...

Reaction mechanisms of various kinds of photocatalysts have been reviewed based on the recent reports, in which various spectroscopic techniques including luminol chemiluminescence photometry, fluorescence probe method, electron spin resonance (ESR), and nuclear magnetic resonance (NMR) spectroscopy were applied. The reaction mechanisms elucidated for bare and modified TiO2 were described indiv...

The aim of this research was to prepare rare metal (Er, Yb)-modified TiO2 nanoparticles by a sol-gel method. The obtained nanoparticles were characterized by BET measurements, UV-Vis spectra and the Laser-induced fluorescence (LIF) method. Visible light photocatalytic activity of the sample was studied by photodegradation of phenol while considering the influence of the dopant concentration. Th...