The production of CO via Reverse Water Gas Shift (RWGS) reaction is a suitable route for CO2 valorization. In this study series modified spinels AB2O4 (A site = Ni, Zn and Cu B site=Fe) are investigated as RWGS catalysts their structure-to-function relationships derived from the changes on A-site cation rationalized. For all ferrite systems, process main activity selectivity governed by B-site ...

We report on measurements of the critical temperature of a harmonically trapped, weakly interacting Bose gas as a function of atom number. Our results exclude ideal-gas behavior by more than two standard deviations, and agree quantitatively with mean-field theory. At our level of sensitivity, we find no additional shift due to critical fluctuations. In the course of this measurement, the onset ...

The shape and shift of the 535.0 nm thallium line resulting from the photodissociation of thallium iodide perturbed by krypton and xenon were investigated at low densities. The Doppler and collision broadening components of the line shape have been determined. The linear dependence of both the Lorentzian half-width and the shift on the perturbing gas density was found and interpreted in terms o...

We perform high-precision measurements of the condensation temperature of a harmonically trapped atomic Bose gas with widely tunable interactions. For weak interactions we observe a negative shift of the critical temperature in excellent agreement with mean-field theory. However for sufficiently strong interactions we clearly observe an additional positive shift, characteristic of beyond-mean-f...

The broadening and shift of the 535.0 nm thallium line resulting from the photodissociation of thallium iodide perturbed by helium, neon and argon were investigated at low densities using a photoelectric Fabry-Perot interferometer. The Doppler and collision broadening components of the line profiles have been determined. Linear variations of both the Lorentzian half-width and the shift of the l...

We observed the filamentation of mid-infrared ultrashort laser pulses (3.9 μm, 80 fs) in molecular gases. It efficiently generates a broadband supercontinuum over two octaves in the 2.5-6 μm spectral range, with a red-shift up to 500 nm due to the Raman effect, which dominates over the blue shift induced by self-steepening and the gas ionization. As a result, the conversion efficiency into the ...

We show that the shift in the transition temperature of the dilute homogeneous Bose gas is nonanalytic in the scattering amplitude a. The first correction beyond the positive linear shift in a is negative and of order a(2)lna. This nonuniversal nonanalytic structure indicates how the discrepancies between numerical calculations at finite a can be reconciled with calculations of the limit a-->0,...

Global gas markets feature two types of suppliers: piped gas and LNG exporters. Pipelines have a high degree of “asset specificity”: once built, they are physically bound to a particular route. LNG is transported by tanker, with a choice of export markets. Put simply: LNG is mobile, pipelines are not. This paper uses game-theoretic modelling to show how its commitment to serving a single market...