نتایج جستجو برای: thermodynamic equilibrium

تعداد نتایج: 164078  

2008
Hernando Quevedo Alberto Sánchez

We apply the formalism of geometrothermodynamics to the case of black holes with cosmological constant in four and higher dimensions. We use a thermodynamic metric which is invariant with respect to Legendre transformations and determines the geometry of the space of equilibrium states. For all known black holes in higher dimensions, we show that the curvature scalar of the thermodynamic metric...

2004
Atsushi Taruya

We investigate the thermodynamic properties of Hamiltonian mean-field(HMF) model as a prototypical long-range system by means of the non-extensive thermostatistics. Especially, the quasi-equilibrium state as extremum state of the generalized Tsallis entropy is studied and its thermodynamic stability is analyzed. Based on these analysis, the connection with quasi-stationary behaviors found in th...

Journal: :The Journal of chemical physics 2014
Folarin Latinwo Kai-Wen Hsiao Charles M Schroeder

Modern materials processing applications and technologies often occur far from equilibrium. To this end, the processing of complex materials such as polymer melts and nanocomposites generally occurs under strong deformations and flows, conditions under which equilibrium thermodynamics does not apply. As a result, the ability to determine the nonequilibrium thermodynamic properties of polymeric ...

2005
Alexander N. Gorban Gregory S. Yablonsky

Everything that is not prohibited is permissible. So, what is prohibited in the course of chemical reactions, heat transfer and other dissipative processes? Is it possible to “overshoot” the equilibrium, and if yes, then how far? Thermodynamically allowed and prohibited trajectories of processes are discussed by the example of effects of equilibrium encircling. The complete theory of thermodyna...

2003
W Z Jiang

The thermodynamic interaction of a free Fermion system is alternatively described by the coupling of particles with the vacuum of a scalar pseudo boson which features a self-interaction. The proper temperature is shown as a Lorentz scalar in a Lorentz invariant framework. At thermodynamic equilibrium, the Lorentz transformation of temperature is investigated based on the conceptions of the rela...

2010
Renata M. Wentzcovitch Zhongqing Wu

Thermodynamic (Anderson 2005) and elastic properties (Musgrave 1970) of minerals provide the fundamental information needed to analyze seismic observations and to model Earth’s dynamic state. The connection between pressure, temperature, chemical composition, and mineralogy that produce seismic velocity gradients, heterogeneities, and discontinuities, can be established with knowledge of thermo...

2009
Hernando Quevedo Alberto Sánchez

We apply the formalism of geometrothermodynamics to the case of black holes with cosmological constant in four and higher dimensions. We use a thermodynamic metric which is invariant with respect to Legendre transformations and determines the geometry of the space of equilibrium states. For all known black holes in higher dimensions, we show that the curvature scalar of the thermodynamic metric...

2008
Vlado A. Lubarda

An analysis of the Gibbs conditions of stable thermodynamic equilibrium, based on the constrained minimization of the four fundamental thermodynamic potentials, is presented with a particular attention given to the previously unexplored connections between the secondorder variations of thermodynamic potentials. These connections are used to establish the convexity properties of all potentials i...

2002
Atsushi Taruya Masa-aki Sakagami

We revisit the issues on the thermodynamic property of stellar self-gravitating system arising from Tsallis’ non-extensive entropy. Previous papers (Taruya & Sakagami, Physica A 307 (2002) 185 (cond-mat/0107494); ibid. (2002) in press (condmat/0204315)) have revealed that the extremum-state of Tsallis entropy characterized by the so-called stellar polytrope has consistent thermodynamic structur...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه پیام نور - دانشگاه پیام نور استان خراسان رضوی - دانشکده شیمی 1388

در این کار تحقیقاتی ابتدا مطالعه سینتیک واکنش پیریدین و 2 کلر پیریدین با کمپلکس پلاتین (ii) به فرمول p-tol)2 (sme2)2])pt]در دماهای 30،20،15،5 و 40 درجه سلسیوس بررسی گردید. که بدلیل سرعت زیاد واکنش محاسبه پارامترهای سینتیکی غیر میسر بود لذا کار ترمودینامیکی جانشینی سه لیگاند از پیریدین و مشتقات آن (2 کلروپیریدین و 2 برموپیریدین) در سه حلال (دی کلرو متان، استن و متانول) در دستور کار قرار گرفت. ب...

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