Abstract This study demonstrates that dibutyltin‐dilaurate (DBTL), commonly used to catalyze condensation‐cured silicone elastomers, causes dynamic behavior in the network, which is attributed catalyst finding a way become part of elastomer network. Furthermore, it establishes by choosing an appropriate silanol‐terminated polydimethylsiloxane (HO‐PDMS‐OH) chain length, gelation system without c...