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A low-coordinate iron(ii) complex (CztBu(PztBu)2)Fe[N(SiMe3)2], 1 bearing an NNN-pincer ligand was prepared and fully characterized. Intramolecular C-H activation on the 5-position of a pyrazole at elevated temperatures was observed. Complex 1 was found to be an efficient and chemoselective pre-catalyst for the hydrosilylation of organo carbonyl substrates.

A solution chemistry synthetic route yields Cs(3)C(60) with a face-centred cubic structure. The described method uses well-established Schlenk techniques and THF as a solvent. The controlled addition of an organo-metallic salt reducing agent prevents the formation of C(60)(4-) salts. The final product can be precipitated from the solution using hexane as an anti-solvent.

Pyrrolo[2,1-a]isoquinoline alkaloids have been prepared via a visible light photoredox catalyzed oxidation/[3 + 2] cycloaddition/oxidative aromatization cascade using Rose Bengal as an organo-photocatalyst. A variety of pyrroloisoquinolines have been obtained in good yields under mild and metal-free reaction conditions.

Herein, we describe simple, fast and reproducible halide ion exchange reactions in CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) at room temperature. Through the simple adjustment of the halide ion concentration, the photoluminescence of these NCs can be tuned over the entire visible region (425-655 nm). Photodetector devices based on entirely inorganic CsPbI3 NCs are demonstrated for the first tim...

A novel macrocyclic organotin(iv) carboxylate {[n-Bu2Sn(O)]9(CH2CH3)2L}·3CH2CH3OH (complex 1) (L = (9-carboxymethyl-1,3,8,10-tetraoxo-3,8,9,10-tetrahydro-1H-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinolin-2-yl)-acetic acid) was generated by the reaction of dibutyltin oxide with amide dicarboxylic acid L and characterized by elemental analysis, IR, (1)H and (13)C NMR spectroscopy. X-ray crystallogr...