It is known that the glass forming-ability (GFA) of bulk metallic glasses (BMGs) can be greatly enhanced via minor element additions. However, direct evidence has been lacking to reveal its structural origin despite different theories hitherto proposed. Through the high-resolution transmission-electron-microscopy (HRTEM) analysis, here we show that the content of local crystal-like orders incre...

Arenetricarbonyl metal complexes ([-phM(CO)3-] and [-biphM(CO)3-]; ph = phenylene, biph = biphenylene, M = Mo, Cr) constructed within Zr-based MOFs act as highly active and selective catalysts for epoxidation of cyclooctene. Catalytic activities of these complexes are enhanced with increasing the pore sizes of Zr-based MOFs.

An atom probe field ion microscopy survey of several bulk metallic glasses including the zirconium-based glasses Z r 1 i 3 4 6 2 s s , 7 5 7 , 5 1 0 2 7 . 5 4 . ~ . ~ . ~ ~ ~ . Z ~ , ~ N ~ , A ~ ~ O C U ~ , ~ N ~ I Z , ~ , and Zr ,,,, T ~ , A ~ , , C U ~ ~ , , N ~ , ~ , ~ , together with two non-zirconium-based glasses Ti3,Zr,,Cu4,NiS, and Mg,,Cu,,Y,,, is presented. Non random distribution of s...

in this work, homogeneous thermochemical co-precipitation method was used to fabricate w-25wt%cu nanocomposite. synthesized nanocomposite powder was calcined and reduced. a hydrogen atmosphere sintering at 1200oc for 105 consolidated the product up to a density close to 98% theoretical density. wear experiment were carried out using a pin-ondisc set up at three normal loads of 5, 10 and 15 n an...

A novel ternary Punica granatum L-Cu/Cu2O/CuO/ZnO nanocomposite was successfully synthesised via green route. In this work, we demonstrate that the green synthesis of metal oxides is more viable and facile compare to other methods, i.e., physical and chemical routes while presenting a potential electrode for energy applications. The prepared nanocomposite was characterised by both microscopic a...

Abstract The influence of CuO/ZrO 2 /ZnO (Cu/Zr/Zn) catalyst modification with Mn, Ni, Ga on the physicochemical properties and activity toward hydrogen production in steam reforming ethanol (SRE) reaction has been evaluated. increase yield lowest selectivity to acetaldehyde were observed upon Cu/Zr/Zn Mn Ga. characterisation spent catalysts revealed changes phase compositions reducibility. In ...

In this study, the high strain rate deformation behavior and the microstructure evolution of Zr-Cu-Al-Ni metallic glasses under various strain rates were investigated. The influence of strain and strain rate on the mechanical properties and fracture behavior, as well as microstructural properties was also investigated. Before mechanical testing, the structure and thermal stability of the Zr-Cu-...

Dual-phase Zr-based thin films synthesized by magnetron co-sputtering and showing competitive growth between amorphous crystalline phases have been reported recently. In such films, the phase grows as columns, while separated cone-shaped regions made of smaller crystallites. this paper, we investigate phenomenon propose a model for development during film growth. We evidence using X-ray diffrac...