a theoretical study of the kinetic and mechanism of 3-aug-cope rearrangement in gas phase was performed usingdet methods at b3lyp levels of theory with 6-3114ig(d,p) bass set at 298.i5k. equilibrium moleculargeometries and harmonic vibrational frequencies of the reactant, transition state did product were calculated. then,rate constant and activation thermodynamics parameters were calculated an...

this study was designed to compare the effectiveness of different activation treatments for activation of in vitro matured oocytes and their developmental potency in mcr2aa medium so as to obtain maximum number of embryos. a total of 1090 cumulus oocyte complexes (coc’s) were collected from 480 ovaries. in vitro matured oocytes were randomly divided into four groups. group 1 in vitro matured oo...

the goal of this study was to determine the effects of the l-type calcium channel blockers verapamil and diltiazem on the currents of voltage-gated potassium channel (fkv1.4δn), an n-terminal-deleted mutant of the ferret kv1.4 potassium channel. measurements were made using a two electrode voltage clamp technique with channels expressed stably in xenopus oocytes. the fkv1.4δn currents displayed...

Accurate partial gamma-ray production cross sections were determined for the prompt and radioactive product decay gamma rays following cold neutron capture in Tc. They can be used for non-destructive assay of technetium by prompt gamma activation analysis (PGAA) and neutron activation analysis (NAA), offering orders of magnitude higher analytical sensitivities than passive gamma-ray counting. A...

the purpose of the present study is to investigate the cytotoxicity/apoptotic effect of 2-chloro-2′-deoxyadenosine, cladribine, (2-cda) in the human breast cancer cell line, mda-mb468 (estrogen receptor negative, er−). mtt [3-(4,5-dimethyl-2-thiazolyl)-2,5-diphenyl-2h tetrazolium bromide] assay, annexin v-fluorescein/pi and hoechst 33258 staining were used to detect cytotoxicity and cell apopto...