The synthesis and functionalization of imines and amines are key steps in the preparation of many fine chemicals and for pharmaceuticals in particular. Traditionally, metal complexes are used as homogeneous catalysts for these organic transformations. Here we report gold–palladium and ruthenium–palladium nano-alloys supported on TiO2 acting as highly efficient heterogeneous catalysts for the on...

This review provides an overview on Pd-based electrocatalysts for the oxygen reduction reaction (ORR) through scientometric analysis and critical methods. The main focus is activity regulation synthetic

In the last years, hydrogen has been considered as a promising energy vector for the oncoming modification of the current energy sector, mainly based on fossil fuels. Hydrogen can be produced from water with no significant pollutant emissions but in the nearest future its production from different hydrocarbon raw materials by thermochemical processes seems to be more feasible. In any case, a mi...

Abstract Ranging from silver‐entrapped dyes and gold‐entrapped enzymes through palladium‐entrapped graphene oxide, molecularly doped metals (or metal organic alloys, MORALs) are active, stable uniquely versatile catalysts in a number of reactions relevance to the chemical industry. Reactions successfully catalyzed by MORALs concern both industry's main sectors, producing bulk fine chemicals. Th...

statement of problem: element release from dental casting alloys into the oral environment is of clinical concern and is considered to be a potential health problem to all patients. purpose: the aim of this study was to investigate the metallic ion release of four base metal alloys. materials and methods: two ni-cr (minalux and supercast) and two co-cr alloys (minalia and wironit) were examined...

Metallic aluminum (Al) is of interest as a reducing agent because of its low standard reduction potential. However, its surface is invariably covered with a dense aluminum oxide film, which prevents its effective use as a reducing agent in wet-chemical synthesis. Pitting corrosion, known as an undesired reaction destroying Al and is enhanced by anions such as F⁻, Cl⁻, and Br⁻ in aqueous solutio...

First principles calculations have become one of the main computational methods in condensed matter physics and physical chemistry due to their high degree of accuracy without the usage of any fitting parameters. Interest has been growing in the engineering disciplines to exploit these properties to predict new materials with desired material properties, greatly accelerating the prototyping of ...