نتایج جستجو برای: merrifield
تعداد نتایج: 202 فیلتر نتایج به سال:
Magnetic fields are considered to be dominant when εB ≥ εK , being εB = B /8π the magnetic energy density and εK = 1/2ρθ 2 the rotation energy density, for a conventional moderate B= 1 μG. They are considered to be negligible when εB < εK for B ∼ 10μG. With no assumption and no theoretical calculation, we show that magnetic fields cannot be ignored in the outer parts of a galaxy like the Milky ...
Orthogonality in organic, polymer, and supramolecular chemistry: from Merrifield to click chemistry.
The concept of orthogonality has been applied to many areas of chemistry, ranging from wave functions to chromatography. But it was Barany and Merrifield's orthogonal protecting group strategy that paved the way for solid phase peptide syntheses, other important classes of biomaterials such as oligosaccharides and oligonucleotides, and ultimately to a term in widespread usage that is focused on...
In Ars Comb. 84 (2007), 85–96, Pedersen and Vestergaard posed the problem of determining a lower bound for the number of independent sets in a tree of fixed order and diameter d. Asymptotically, we give here a complete solution for trees of diameter d ≤ 5. The lower bound is 5 and we give the structure of the extremal trees. A generalization to connected graphs is stated.
The extent of biological inactivation and of the degradation of the RNA after reaction of bacteriophage R17 with ethyl methanesulphonate, isopropyl methanesulphonate and N-ethyl-N-nitrosourea was studied. Formation of breaks in the RNA chain probably results from hydrolysis of phosphotriesters formed in the alkylation reactions. Near neutral pH the ethyl and isopropyl phosphotriesters are suffi...
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