The study of water–hydrocarbon phase equilibria is very important for both scientific and industrial purposes. This work a thorough investigation the predictive capability SAFT-VR Mie equation state (EoS) aqueous hydrocarbon equilibria, including n-alkanes, alkenes, cycloalkanes, branched alkanes, aromatic hydrocarbons. For alkenes alkyl benzenes, induced association (solvation) with water cons...