The effects of confinement in carbon nanotubes on Fischer-Tropsch (FT) activity, selectivity and lifetime of Carbon NanoTubes (CNTs) supported iron catalysts are reported. A method was developed to control the position of the catalytic sites on either inner or outer surface of carbon nanotubes. TEM analyses revealed that more than 80% of iron oxide particles can be controlled to be position...

FT-IR and FT-Raman spectra of hirudin have been recorded from the native solid hirudin. The conformation of the molecule has been discussed on the basis of IR and Raman data. It has been concluded that hirudin molecule has a mixed a-helix and random coil conformation.

The effects of electronic properties of inner and outer surfaces of Carbon Nano Tubes (CNTs) on the deactivation of cobalt Fischer-Tropsch (FT) catalysts were studied. The comparative characterization of the fresh and used catalysts by TEM, XRD, TPR, BET and H2 chemisorption showed that cobalt re-oxidation, cobalt-support interactions and sintering are the main sources o...

objective: the use of hema as a biocompatible material in dentin bonding systems and its potential for clinical applications has been well established. excess water can affect conversion of bonding resins. the aim of this study was to survey the effect of water on the degree of conversion of hema by fourier transform infra-red spectroscopy (ft-ir). materials and methods: in this experimental st...

Correlating Pressure Drop and Liquid Holdup Werner van der Merwe , Dylan Loudon and Willie Nicol a Department of Chemical Engineering, University of Pretoria, South Africa b Fischer-Tropsch Refinery Catalysis, Sasol Technology Research and Development # Correspondence to: Department of Chemical Engineering, University of Pretoria, Pretoria 0002, South Africa, Tel: +27-12-420-3796, Fax: +27-12-3...

While fossil oil reserves have been receding, the demand for diesel and gasoline has growing. In recent years, syngas of biomass origin emerging as a viable feedstock Fischer-Tropsch (FT) synthesis, process manufacturing synthetic diesel. This paper reports optimization quality to match FT synthesis requirement. The model maximizes thermal efficiency under constraint <math xmlns="http://www.w3....

Water increases Fischer-Tropsch synthesis (FTS) rates on Ru through H-shuttling processes. Chemisorbed hydrogen (H*) transfers its electron to the metal and protonates the O-atom of CO* to form COH*, which subsequently hydrogenates to *HCOH* in the kinetically relevant step. H2 O also increases the chain length of FTS products by mediating the H-transfer steps during reactions of alkyl groups w...

Synchrotron X-ray diffraction coupled to atomic pair distribution function analysis and Reverse Monte Carlo simulations is used to determine the atomic-scale structure of Ru nanoparticle catalysts for the Fischer-Tropsch reaction. The rate of CO hydrogenation strongly correlates with the abundance of surface atoms with coordination numbers of 10 and 11. DFT calculations confirm that CO dissocia...

Converting coal or natural gas into synthetic crude oil (Fischer-Tropsch method) is a costly and difficult undertaking associated with long development timeframes of up to a decade or longer, which may no longer be available (Hirsch, 2006). It would also result in a net increase in carbon emissions unless carbon is captured and geo-sequestered. This technology remains untried, would be financia...