نتایج جستجو برای: ring inversion

تعداد نتایج: 164449  

2009
Ge-Jiang Xiao Chao Wei

The title compound, C(15)H(13)N(3)O(4), was synthesized by the reaction of equimolar quanti-ties of 2-methoxy-benzaldehyde and 2-nitro-benzohydrazide in methanol. The dihedral angle between the two substituted benzene rings is 68.3 (2)°. In the crystal structure, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.

2014
B. Narayana Vinutha V. Salian Balladka K. Sarojini Jerry P. Jasinski

In the title compound, C21H23ClN2O, the dihedral angle between the benzene rings is 83.2 (6)°, while the mean plane of the pyrazole ring [r.m.s. deviation = 0.043 (1) Å] makes dihedral angles of 3.4 (3) and 86.2 (1)° with the benzene rings. In the crystal, a pair of weak C-H⋯O inter-actions between the benzene ring and the propan-1-one group link the mol-ecules into an inversion dimer with an R...

2014
Daron E. Janzen Laura E. Crepeau Benjamin D. Hageseth James W. Wollack

In the title compound, C13H10N2O4, the nitro groups are twisted significantly relative to the benzene rings [dihedral angles = 16.64 (18) and 28.02 (11)°]. The benzene groups are nearly perpendicular to each other [dihedral angle = 87.72 (6)°]. Short inter-molecular N⋯O and C⋯O [2.981 (2) and 3.060 (2) Å, respectively] contacts suggest possible weak π-inter-actions between nitro groups and betw...

2013
P. A. Suchetan B. S. Palakshamurthy G. R. Mamatha Vijith Kumar N. R. Mohan S. Sreenivasa

In the title compound, C14H12ClNO4S, the dihedral angle between the chloro- and meth-oxy-substituted benzene rings is 87.40 (1)°. In the crystal, adjacent mol-ecules form inversion-related dimers through strong N-H⋯O hydrogen bonds, generating R 2 (2)(8) loops. The dimers are further connected through two C-H⋯O inter-actions that form C(11) chains and R 2 (2)(14) loops. Aromatic π-π stacking in...

2011
Vinola Z. Rodrigues Sabine Foro B. Thimme Gowda

In the title compound, C(15)H(16)ClNO(2)S, the C-SO(2)-NH-C torsion angle is -61.15 (16)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 38.8 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

2007
Xiao-li Wang Huaying Bao

In the title compound, [Fe(C(17)H(20)NO(2)Si)(2)], the Fe atom is situated on a crystallographic centre of inversion, leading to a perfectly staggered conformation of the Cp rings.

2011
Vinola Z. Rodrigues Sabine Foro B. Thimme Gowda

In the title compound, C(14)H(13)Cl(2)NO(2)S, the C-SO(2)-NH-C torsion angle is -71.4 (4)°. The sulfonyl and aniline benzene rings are tilted relative to one another by 44.6 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

2008
Zhi-gang Yin Heng-yu Qian He-ping Li Jie Hu Chun-xia Zhang

In the approximately planar molecule of the title compound, C(11)H(8)N(4)O(4)S, the dihedral angle between the thio-phene and benzene rings is 5.73 (10)°. In the crystal structure, bifurcated inter/intra-molecular N-H⋯(O,O) hydrogen bonds are present. The intermolecular links lead to inversion dimers containing an R(2) (2)(12) graph-set motif.

2010
Huanyu Liu

In the title compound, C(14)H(9)ClN(4)O(5), the mol-ecule exists in a trans geometry with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 62.7 (2)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops.

2013
Christopher Goh Lilliana S. Morris Michael P. Girouard Tamuka Chidanguro Jerry P. Jasinski

The title compound, C18H24N4, resides on a crystallographic inversion centre, so that the asymmetric unit comprises one half-mol-ecule. The piperazine ring adopts a chair conformation, with the mean planes of the two equatorial pyridine rings parallel to each other and separated by 2.54 (3) Å. No classical hydrogen bonds are observed.

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