Spin crossover (SCO) complexes possess a bistable spin state that reacts sensitively to changes in temperature or excitation with light. These effects have been well investigated in solids and solutions, while technological applications require the immobilization and contacting of the molecules at surfaces, which often results in the suppression of the SCO. We report on the thermal and light-in...

Manganocene reacts with LiE(SiMe(3))(2) (E = P or As) to give [(η(5)-Cp)Mn{μ-E(SiMe(3))(2)}](2), where E = P (1) or As (2). The temperature dependence of the magnetic susceptibility in 1 and 2 is due to antiferromagnetic exchange and to spin-crossover (SCO). Compound 2 shows two-step SCO with hysteresis, involving high-spin (S = 5/2) and intermediate-spin S = (3/2) Mn(II).

Phase-resolved VLT spectroscopy of the bursting Low Mass X-ray Binaries 4U 1636536/V801 Ara and 4U 1735-444/V926 Sco is presented. Doppler images of the NIII λ4640 Bowen transition reveal compact spots which we attribute to fluorescent emission from the donor star and enable us to define a new set of spectroscopic ephemerides. We measure Kem = 277 ± 22 km s and Kem = 226 ± 22 km s from the NIII...

The intense galactic X-ray source GX 349+2 (Sco X-2) belongs to the class of persistently bright low-mass X-ray binaries called Z-sources. GX 349+2, although observed in X-rays for more than 30 years, has only recently been optically identified with a 19th mag star. Of the six known Z-sources, only two (Sco X-1 and Cyg X-2) have been studied in the optical. It has been suggested that Z-sources ...

The spin-crossover (SCO) phenomenon between a high-spin and a low-spin state has attracted much attention in the field of materials science. Among the various kinds of SCO complexes, the triazole-bridged iron(II) polymeric chain system, [Fe(II)(R-trz)3]X2·xH2O (where trz is triazole and X is the anion), exhibiting the SCO phenomenon with thermal hysteresis around room temperature, has been exte...

BACKGROUND AND PURPOSE Our previous model of spinal cord injury (SCI) included six dogs undergoing 30-minute compression with a balloon in the subarachnoid space. We determined whether various balloon sizes and compression times creates a gradation of injuries. METHODS In 17 dogs (including our original six), angioplasty balloons 2, 4, or 7 mm in diameter (2 cm long) were inflated at T6 for 3...

Human SCO1 and SCO2 are paralogous genes that code for metallochaperone proteins with essential, but poorly understood, roles in copper delivery to cytochrome c oxidase (COX). Mutations in these genes produce tissue-specific COX deficiencies associated with distinct clinical phenotypes, although both are ubiquitously expressed. To investigate the molecular function of the SCO proteins, we chara...

In this paper we study new stochastic approximation (SA) type algorithms, namely, the accelerated SA (AC-SA), for solving strongly convex stochastic composite optimization (SCO) problems. Specifically, by introducing a domain shrinking procedure, we significantly improve the large-deviation results associated with the convergence rate of a nearly optimal AC-SA algorithm presented in [4]. Moreov...

Differential Strömgren uvby photometry of ζ1 Sco collected during the time interval 1982-1995 is analysed together with new V BLUW photometry with a complementary discussionof unpublishedJHKLM data.We report the discovery of a∼ 1750-2200 d regular oscillation of amplitude∼ 0. m01 in all bands, and pulsation-like oscillations with at least one frequency f1 = 0.03155 (P ∼ 32 days) and a possible ...

We investigate how intellectual property (IP) enforcement against open source software (OSS) projects affects OSS adoption. We hypothesize that adoption of OSS sharing similar technological features with the litigated OSS technology and OSS typically used within organizations and complementary with the litigated OSS would be disproportionately affected by IP enforcement. We examine two widely p...