نتایج جستجو برای: ring inversion

تعداد نتایج: 164449  

2012
Mohammad Reza Melardi Maryam Aghamohamadi Jafar Attar Gharamaleki Mohammad Kazem Rofouei Behrouz Notash

The title mol-ecule, C(13)H(11)Cl(2)N(3)O, is almost planar and adopts a trans conformation with respect to the -N=N- bond; the dihedral angle between the rings is 3.47 (2)°. The N-N bond lengths indicate the presence of single- and double-bond characters and hence the -N=N-NH- moiety. In the crystal, inversion dimers linked by pairs of N-H⋯Cl hydrogen bonds occur, and C-H⋯π and π-π stacking in...

2010
B. Thimme Gowda Sabine Foro P. G. Nirmala Hartmut Fuess

In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N-C bonds in the C-SO(2)-NH-C segments have gauche torsions with respect to the S=O bonds. The dihedral angle between the two benzene rings is 68.6 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds.

2012
U. Chaithanya Sabine Foro B. Thimme Gowda

In the title compound, C12H9ClN2O4S, the dihedral angle between the benzene rings is 70.60 (11)°. An intra-molecular N-H⋯Cl contact occurs. In the crystal, mol-ecules form inversion dimers via pairs of N-H⋯O hydrogen bonds.

2012
Nabil El Brahmi Mohammed Benchidmi El Mokhtar Essassi Sonia Ladeira Lahcen El Ammari

The fused five- and six-membered rings in the title mol-ecule, C10H9N3O2, are essentially coplanar, the largest deviation from the mean plane being 0.012 (1) Å for the C atom linked to the nitro group. The fused-ring system makes a dihedral angle of 11.34 (6)° with the nitro group, leading to a syn-periplanar conformation. The plane through the atoms forming the allyl group is nearly perpendicu...

2012
V. Sughanya N. Sureshbabu

In the title compound, C(24)H(29)BrO(6), the dihedral angle between the cyclo-hexenone mean planes is 57.63 (2)° while the dihedral angles between the benzene ring and the cyclo-hexenone mean planes are 58.42 (2) and 69.08 (3)°. The two cyclo-hexenone rings both show an envelope conformation, with the C atom bearing two methyl groups as the flap atom in each ring. Two intra-molecular O-H⋯O hydr...

2009
Li-Hua Huo Shan Gao Seik Weng Ng

In the crystal structure of the title compound, C(18)H(14)N(4), the mol-ecule assumes site symmetry with the centroid of the benzene ring located on the inversion center. The mol-ecule is almost flat, with a dihedral angle of 2.70 (9)° between the pyridine and benzene rings.

2011
Vinola Z. Rodrigues Sabine Foro B. Thimme Gowda K. Shakuntala

In the title compound, C(13)H(10)Cl(3)NO(2)S, torsion angle of the C-SO(2)-NH-C group in the mol-ecule is -58.57 (26)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 84.2 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

2012
S. Jeyaseelan H. C. Devarajegowda R. Sathishkumar Agnes Sylvia D’souza Alphonsus D’souza

In the title compound, C(11)H(11)FN(4)S, the dihedral angle between the 1,2,4-triazole ring and the benzene ring is 25.04 (12)° and an intra-moleuclar C-H⋯S inter-action leads to an S(6) ring. In the crystal, inversion dimers linked by pairs of N-H⋯S hydrogen bonds generate R(2) (2)(8) loops.

2011
Liuming Wu Cong Deng Yan Yang

The title compound, C(23)H(18)O(4), is a 1,4-enedione compound which contains a naphthalene ring and a benzene ring. The dihedral angle between the ring systems is 74.9 (2)°. In the crystal, the mol-ecules form π-π stacking inter-actions between naphthalene rings of inversion-related mol-ecules, with an inter-planar spacing of 3.499 (2) Å.

2008
T. Augustine Scholastica Mary Vithiya V. Ramkumar Charles C. Kanakam

In the title compound, C(17)H(14)O(3), the dihedral angle between the phenyl ring and the benzene ring of the chromanone moiety is 67.78 (3)°. The six-membered heterocyclic ring of the chromanone moiety adopts a half-chair conformation. The structure is stabilized by weak inter-molecular C-H⋯O inter-actions that link the mol-ecules into inversion dimers.

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