We explore the peculiar steady component of a sessile drop response to MHz order vibration, found to be dependent on its initial wettability. Placed on a vibrating hydrophobic substrate, the drop elongates vertically in the direction of the incident sound wave while remaining hydrophobic. In contrast, the drop is seen to spread on a slightly hydrophilic substrate. We elucidate this discrepancy ...

Elastic and quasielastic neutron scattering experiments have been used to investigate the dynamics of methyl groups in a protein-model hydrophobic peptide in solution. The results suggest that, when the hydrophobic side chains are hydrated by a single hydration water layer, the only allowed motions are confined and attributed to librational and rotational movement associated with the methyl gro...

abstract among synthetic carriers, dendrimers with the more flexible structure have attracted a great deal of researchers' attention in the field of gene delivery. followed by the promising results upon hydrophobic modification on polymeric structures in our laboratory, alkylcarboxylated poly (propylenimine)-based carriers were synthesized by nucleophilic substitution of amines with alkyl moiet...

Soil contamination by heavy metals through the application of a phosphate fertilizer is key issue for sustainable agriculture. Among contaminants, cadmium (Cd) considered most hazardous to human beings’ health and surrounding environment. X-ray diffraction (XRD), combined with binocular mineralogical analysis chemical analysis, was used determine C(I) C(II) layers’ composition. In (+71 µm)-size...

lateral flow assay, a simple and rapid test to detect various agents; have found many applications in different fields. one of the most important issues in the construction of a lateral flow assay is the increasing of its sensitivity and efficiency by processing of analytical layer. this study, aimed to investigate the performance of, nellulose, nitrocellulose, nylon and pvd as different analyt...

The impact of small nonionic hydrophobic molecule, trioxyethylene monododecyl ether (C12EO3), on the viscoelastic properties of aqueous solutions of cetylpyridinium chloride (CPC) is studied. As the C12EO3 concentration increases, the viscosity passes through a maximum. Dynamic rheological measurements revealed a comprehensive picture of how C12EO3 affects the different length scales in the ent...

Responsive photonic crystals have been developed for chemical sensing using the variation of optical properties due to interaction with their environment. Photonic crystals with tunability in the visible or near-infrared region are of interest for controlling and processing light for active components of display, sensory or telecommunication devices. Here, we report a hydrophobic block-hydrophi...

The mechanisms by which hydrophobic molecules, such as long-chain fatty acids, enter cells are poorly understood. In Gram-negative bacteria, the lipopolysaccharide layer in the outer membrane is an efficient barrier for fatty acids and aromatic hydrocarbons destined for biodegradation. We report crystal structures of the long-chain fatty acid transporter FadL from Escherichia coli at 2.6 and 2....

The hedgehog-shaped {Mo368} cluster shows unique electronic (extremely high extinction coefficient) and structural features, especially regarding its size, the high number of delocalized electrons which allows to measure the surface enhanced Raman scattering (SERS) spectrum and the option for coordination chemistry inside the cavity. Its relative instability in aqueous solution can be overcome ...

Superhydrophobic and superhydrophilic properties of chemically-modified graphene have been achieved in larger-area vertically aligned few-layer graphene nanosheets (FLGs), prepared on Si (111) substrate by microwave plasma chemical vapor deposition (MPCVD). Furthermore, in order to enhance wettability, silicon wafers with microstructures were fabricated, on which graphene nanosheets were grown ...