نتایج جستجو برای: dehydration of alcohols

تعداد نتایج: 21165385  

Journal: :journal of sciences islamic republic of iran 0

self-association of alcohols; including ethanol, methanol, cyclopentanol and octanol in separate mixtures with inert solvents have been studied using ft-ir spectroscopy. except for the band at 3640 cm–1 in the ir spectrum of the alcohols which is due to the monomer species, the presence of other bands in the region of stretching vibrational frequencies of oh (3100-3700 cm–1) are attributed to t...

Aluminosilicate gel precursor having mullite composition was synthesized from inorganic salts of aluminum and silicon by employing the sol-gel method. Chemical analysis, surface area and bulk density measurements were performed to characterize the dried gel. The course of the mullitization was examined by FT-IR analysis which confirmed the diphasic nature of the gel. ...

Journal: :iranian chemical communication 0
abbas amini manesh payame noor university, hamedan ardeshir khazaei faculty of chemistry, bu-ali sina university, p.o. box 651783868, hamedan, iran maedeh gohari department of chemistry, payame noor university, 19395-4697 tehran, i. r. of iran mahdieh chegeni department of chemistry, faculty of science, ayatollah ozma boroujerdi university, boroujerd, iran shahnaz saednia young researchers & elites club, toyserkan branch, islamic azad university, toyserkan, iran

methoxymethylation of a variety of alcohols was performed using formaldehyde dimethyl acetal in the presence of 1,3-dichloro-5,5-dimethyl hydantoin [dcdmh] and poly n,n′-dibromo-n-ethyl naphthyl-2,7-disulfonamide [pbns] as catalysts at room temperature and under solvent-free conditions. our experiments show that primary and secondary alcohols can be smoothly converted into the corresponding mom...

Journal: :Chemical communications 2012
Christophe Berini Oscar Navarro

The use of in situ generated (NHC)-Ni catalytic species (NHC = N-heterocyclic carbene) allows for the synthesis, in short reaction times, of a variety of tertiary alcohols from secondary alcohols through a domino oxidation-addition protocol.

Journal: :iranian journal of otorhinolaryngology 0
hassan boskabadi neonatal research center, ghaem hospital, mashhad university of medical sciences, mashhad, iran. farnaz anvarifar neonatal research center, ghaem hospital, mashhad university of medical sciences, mashhad, iran. navid nourizadeh department of otorhinolaryngology, ghaem hospital, mashhad university of medical sciences, mashhad, iran.

introduction: neonatal hypernatremia dehydration (nhd) is a dangerous condition in neonates, which is accompanied by acute complications (renal failure, cerebral edema, and cerebral hemorrhage) and chronic complications (developmental delay). children begin learning language from birth, and hearing impairment interferes with this process. we assessed the hearing status of infants with hypernatr...

Journal: :journal of nanostructures 0
amin ebadi department of chemistry, kazerun branch, islamic azad university sanaz shojaei department of chemistry, kazerun branch, islamic azad university

unsubstituted phthalocyanines of co, fe and mn supported on zinc oxide nanoparticles were prepared and were well characterized with x-ray diffraction (xrd) and scanning electron microscopy (sem). the oxidation of alcohols with tert-butylhydroperoxide (tbhp), in the presence of metallophthalocyanines (mpc) supported on zinc oxide nanoparticles was investigated. these mpc/zno nanocomposites were ...

T3P/DMSO is shown to be an effective and mild reagent for the one-pot synthesis of furo[2,3-d]pyrimidine-2,4(1H,3H)-diones from a variety of alcohols. Alcohols are oxidized in situ to aldehydes under mild conditions, which undergo a three-component reaction with N,N'-dimethylbarbituric acid and various isocyanides to afford furo[2,3-d]pyrimidine-2,4(1H,3H)-diones in good yields.

Journal: :journal of sciences islamic republic of iran 0

trimethylsilylation of a variety of alcohols and phenols, in the presence of silica chloride, using hexamethyldisilazane (hmds) in solution and under solvent-free conditions is reported. trimethylsilyl ethers were formed in excellent yields both for aliphatic alcohols and phenols without having an electron-withdrawing group. in addition, sio2-cl can be recovered and reused after drying.

Mn(II) salen complex immobilized on nano silicagel was prepared by incorporating Mn(II) salen complex into a nanosilica matrix and characterized by TGA, XRD, atomic absorption spectroscopy and was successfully applied as catalyst for the oxidation of alcohols. Oxidation of a series of alcohols in acetonitrile over immobilized Mn(II) salen complex using tetrabutylammonium peroxymonosulfate (TBAO...

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