نتایج جستجو برای: au catalyst
تعداد نتایج: 121787 فیلتر نتایج به سال:
We report the microwave synthesis and characterization of Au and Pd nanoparticle catalysts supported on CeO2, CuO, and ZnO nanoparticles for CO oxidation. The results indicate that supported Au/CeO2 catalysts exhibit excellent activity for low-temperature CO oxidation. The Pd/CeO2 catalyst shows a uniform dispersion of Pd nanoparticles with a narrow size distribution within the ceria support. A...
A series of nanostructured Pt-Au/MOx-CeO₂ (M = Mn, Fe, Ti) catalysts were prepared and their catalytic performance for the co-oxidation of carbon monoxide (CO) and hydrogen (H₂) were evaluated at room temperature. The results showed that MOx promoted the CO oxidation of Pt-Au/CeO₂, but only the TiO₂ could enhance co-oxidation of CO and H₂ over Pt-Au/CeO₂. Related characterizations were conducte...
Introduction Bulk gold is a chemically inert metal, and had previously been disregarded as a candidate for catalytic applications [1]. Haruta’s pioneering work [2] showed exceptional reactivity on gold nanoparticles of 2-5 nm in diameter. Among reactions, the low temperature CO oxidation [3] on Au has created a strong interest. Model catalyst samples, which consist of planar metal oxide surface...
Layer-structured group III chalcogenides have highly anisotropic properties and are attractive materials for stable photocathodes and battery electrodes. We report the controlled synthesis and characterization of layer-structured GaSe nanowires via a catalyst-assisted vapor-liquid-solid (VLS) growth mechanism during GaSe powder evaporation. GaSe nanowires consist of Se-Ga-Ga-Se layers stacked t...
Single crystalline stepped-surfaced GeSe2 nanobelts (NBs) were synthesized by vapor transport and deposition method with the presence of Au catalyst. The NBs were grown via VLS mechanism with catalytic Au–Ge–Se alloy droplet formed at the tip of the NBs. The dynamic reshaping of the catalyst particle leads to formation of steps along the NB. Photodetectors comprising individually isolated NBs w...
The morphological change of silicon macropore arrays formed by metal-assisted chemical etching using shape-controlled Au thin film arrays was investigated during anisotropic chemical etching in tetramethylammonium hydroxide (TMAH) aqueous solution. After the deposition of Au as the etching catalyst on (111) silicon through a honeycomb mask prepared by sphere lithography, the specimens were etch...
Controlling the electronic structure and surface strain of a nanoparticle catalyst has become an important strategy to tune and to optimize its catalytic efficiency for a chemical reaction. Using density functional theory (DFT) calculations, we predicted that core/shell M/CuPd (M = Ag, Au) NPs with a 0.8 or 1.2 nm CuPd2 shell have similar but optimal surface strain and composition and may surpa...
BACKGROUND The introduction of an heterogeneously catalyzed gold-based alcohol oxidation process of broad applicability using a clean primary oxidant would be highly desirable. Gold is non toxic and carbonyl and carboxyl compounds are widely used to produce medicines, plastics, colorants, paints, detergents, fragrances, flavors, and other valued functional products. RESULTS The sol-gel entrap...
The water-gas shift (WGS) reaction (where carbon monoxide plus water yields dihydrogen and carbon dioxide) is an essential process for hydrogen generation and carbon monoxide removal in various energy-related chemical operations. This equilibrium-limited reaction is favored at a low working temperature. Potential application in fuel cells also requires a WGS catalyst to be highly active, stable...
Au nanoparticles are efficient catalysts for the vapour–solid–liquid (VLS) growth of semiconductor nanowires, but Au poses fundamental reliability concerns for applications in Si semiconductor technology. In this work we show that the choice of catalysts for Si nanowire growth can be broadened when the need for catalytic precursor dissociation is eliminated through the use of plasma enhancement...
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