Thiol monolayer-protected Au clusters (MPCs) were prepared using dendrimer templates, deposited onto a high-surface-area titania, and then the thiol stabilizers were removed under H2/N2. The resulting Au catalysts were characterized with transmission electron microscopy, X-ray photoelectron spectroscopy, and infrared spectroscopy of adsorbed CO. The Au catalysts prepared via this route displaye...

germanium nanowires (genws) were synthesized using chemical vapor deposition (cvd) based on vapor–liquid–solid (vls) mechanism with au nanoparticles as catalyst and germanium tetrachloride (gecl4) as a precursor of germanium. au catalysts were deposited on silicon wafer as a thin film, firstly by sputtering technique and secondly by submerging the silicon substrates in au colloidal solution, wh...

For comparative means, a current Au-TiO 2 catalyst was used or order to benchmark current standards for nano-Au catalysts. The Aurolite® catalyst is currently the only commercially produced Au-TiO 2 catalyst comprising of 1% Au (by mass) loaded on P25 type TiO 2 comprising approximately 20% rutile and 80% anatase. A second batch of catalysts was examined where the catalyst composition was simil...

The controllable preparation of nano-gold catalyst maintains a challenge. Except the parameters have been revealed before, here we'd like to show that controllable preparation of active nano-gold catalyst can be achieved using chlorine as an indicator. By tracing the chlorine concentration in the washing step, a series of Au/Fe2O3 catalysts were prepared with co-precipitation method. The applyi...

In our former work [Catal. Today 174 (2011) 127], 12 heterogeneous catalysts were screened for CO oxidation, and Au-ZnO/Al2O3 was chosen and optimized in terms of weight loading of Au and ZnO. The present study follows on to consider the impact of process parameters (catalyst preparation and reaction conditions), in conjunction with catalyst composition (weight loading of Au and ZnO, and total ...

Highly active, supported Au−Pd catalysts have been tested for catalyzing benzyl alcohol oxidation in a siliconglass micropacked bed reactor. The effects of Au−Pd composition and anion content during catalyst preparation on catalyst deactivation were studied, and a relationship between the deactivation rate and the amount of Cl− and Au used in the catalyst formulation was found. While Au aids in...

When Au is subdivided to the nanoscale its reactivity changes from an inert nature to one of incredible reactivity which is not replicated by other catalysts. When dispersed onto metal oxides such as TiO2, nano-Au has shown high reactivities for a multitude of reduction and oxidation reactions of industrial importance with potential and current uses such as, CO oxidation, NO x reduction, purifi...

Diarylamines are an important class of widely utilized chemicals, and development of diverse procedures for their synthesis is of great importance. Herein, we have successfully developed novel versatile catalytic procedures for the synthesis of diarylamines through acceptorless dehydrogenative aromatization. In the presence of a gold-palladium alloy nanoparticle catalyst (Au-Pd/TiO2), various s...

A detailed study of the valence state and distribution of the AuCl3/AC catalyst during the acetylene hydrochlorination deactivation process is described and discussed. Temperature-programmed reduction and X-ray photoelectron spectral analysis indicate that the active Au(3+) reduction to metallic Au(0) is one reason for the deactivation of AuCl3/AC catalyst. Transmission electron microscopy char...

A rotaxane-based Au catalyst was developed and the effect of the mechanical bond on its behavior was studied. Unlike the non-interlocked thread, the rotaxane requires a catalytically innocent cofactor, the identity of which significantly influences both the yield and diastereoselectivity of the reaction. Under optimized conditions, Au(I) (the catalyst), Ag(I) (to abstract the Cl(-) ligand), and...