stereoisograms of octahedral complexes are classified into five types (type i--typev) under the action of the corresponding rs-stereoisomeric group. their enumeration is accomplished in a type-itemized fashion, where fujita's proligand method developed originally for combinatorial enumeration under point groups (s. fujita, theor. chem. acc., 113, 73--79 (2005)) is extended to meet the requireme...

several novel mononuclear zn(ii) complexes, [zn(bpy)l2], where bpy=2,2’-bipyridine and l=monoanions of phenylcyanamide (pcyd), 4-methylphenylcyanamide (4-mepcyd), 3,5-dimethylphenylcyanamide(3,5-me2pcyd),4-methoxyphenylcyanamide(4-meopcyd), 3,5-dimeth-oxyphenylcyanamide (3,5-meo2pcyd), 3-chlorophenylcyanamide (3-clpcyd), 2,3-dichlorophenyl-cyanamide (2,3-cl2pcyd), 4-bromophenylcyanamide (4-brpc...

the interaction between 4, 7, 13, 16, 21, 24 - hexaoxa-1,10 - diazabicyclo [8.8.8] hexacosane (c222) and 7,7,8,8- teracyanoquinodimethane (tcnq) has been studied in chloroform at 25°c. the results indicate a two step mechanism. at the first step, two adducts (assign as p1 and p2) are formed through equilibrium reactions. in continue and through nonequilibrium reactions the adducts are converted...

the natural vibrations of clamped annular isotropic sector plates are analyzed using the extended kantorovich method (ekm). a conformal mapping is used to transform a sector with identified geometry to a rectangular plate which the solution is available in literature and solved by dalaei and kerr [1] using ekm. the developed iterative scheme converges very rapidly to the final result. the obtai...

enaminones are those structures made up three various functional groups including carbonyl, alkeneand amine groups which arelocated along with each other in a conjugate fashion. these compoundsare of much attention due to special characteristics and numerous applications. in the paper, sixvarious enaminone structures were theoretically optimized and after concluding, were compared withequivalen...

for the first time, dioxomolybdenum(vi) complex with the general formula [moo2l2] containing a n-o bidentate ligands (hl=2-(o-aminophenyl)- benzimidazole) has been used for the oxidation of sulfides. elemental analyses (carbon, hydrogen, nitrogen), ft-ir and uv-visble spectra and 1hnmr analysis agree well with the proposed stoicheiometry of the complex [moo2l2].  a variety of sulfides were smoo...

three new complexes of formula [pd(bpy)(r-nh-css)] cl (where bpy is 2/2′- bipyridine, and r-nh-css is butylamine, hexylamine- and octyamine-dithiocabamate anion) have been synthesized by university of sistan and blachostan. these complexes have been characterized by spectroscopic methods such as ultraviolet-visible, infrared and 1h-nmr as well as conductivity measurements and chemical analysis....

almabulage complex is located in the north of asadabad city, northwestern hamedan province, in sanandaj-sirjan structural zone. the complex includes several types of low-grade metamorphosed rocks with various protoliths as well as two intrusion having different chemical compositions of synogranite and gabbro. the synogranite intrusion rock has perthite and granophyric co-growths textures and au...

in the present study, a simple and sensitive extractive spectrophotometric method is described for determination of buspirone. the method is based on the reaction of buspirone and bromocresol green. the ion-pair complex was quantitatively extracted into chloroform at ph 2.3 followed by spectrophotometric determination at 415 nm. the complex was stable up to 2 days and obeyed beer's law over the...