Fifteen commercial titania (titanium(IV) oxide; TiO 2) powders were modified with gold by photodeposition to prepare photocatalysts that work under irradiation with light in the visible range (vis). The gold-modified titania (Au/TiO 2) powders were characterized by diffuse reflectance spectroscopy (DRS), field-emission scanning electron microscopy (FE-SEM), scanning transmission microscopy (STE...

The coating of solid surfaces with inorganic materials is a promising approach not only to impart various functionalities but also to modify physicochemical properties that are affected by the geometry/structure of the coating. In this study, a silica-hexadecyltrimethylammonium (silica-CTA) hybrid layer was deposited on monodispersed spherical particles composed of titania and octadecylamine (t...

A carbon foam using coal tar pitch as precursor was prepared and investigated as support for titanium oxide for the photocatalytic degradation of phenol. The performance of the carbon foam/titania composite was compared to those of unsupported titania and other activated carbon composites from the literature. The photodegradation rate of phenol over the catalysts under UV illumination was fitte...

Nanocrystalline titanium dioxide (nano-TiO(2)) is an important material used in commerce today. When designed appropriately it can generate reactive species (RS) quite efficiently, particularly under ultraviolet (UV) illumination; this feature is exploited in applications ranging from self-cleaning glass to low-cost solar cells. In this study, we characterize the toxicity of this important clas...

microwave energy has potential for the efficient heating of minerals. minerals or materials, which couple to microwave energy are called dielectrics and many valuable minerals are found to be dielectric. the mineral ilmenite is one which shows good dielectric heating characteristics. in this paper, the effect of microwave heat energy on the partial reduction of oxidized ilmenite oxidized in ...

Memristive behavior is defined as a resistive switching loop which can be observed from the current-voltage (I-V) characteristic of a material. This paper reports the application of TiO2 (titania) nanostructures as an active layer for a memristive device instead of using titania thin film in nanoscale thickness as reported by other researchers. 60 nm thickness of titania thin film was deposited...

The current generation of advanced gravitational wave detectors utilize titania-doped tantala/silica multilayer stacks for their mirror coatings. The properties of the low-refractive-index silica are well known; however, in the absence of detailed direct measurements, the material parameters of Young's modulus and coefficient of thermal expansion (CTE) of the high refractive index material, tit...

Modification of titania with copper is a promising way to enhance the photocatalytic performance of TiO2. The enhancement means the significant retardation of charge carriers’ recombination ratio and the introduction of visible light activity. This review focuses on two main ways of performance enhancement by copper species—i.e., originated from plasmonic properties of zero-valent copper (plasm...

Titanium-substituted silicalites, prepared from two different silicalite precursors, are characterized using Raman spectroscopy, X-ray absorption spectroscopy, pyridine adsorption, and methanol oxidation. The silicalite precursors used are tetraethyl orthosilicate and Ludox AS 40. Two different types of titania species are observed in the titania silicalites. Below 1.6 mole% Ti/(Ti + Si), a dis...

Rutile-phase TiO2 nanotube arrays without broken walls were formed by annealing of anodically formed nanotubes in a propane flame at 650 °C and in air at 750 °C. An unusual morphological transformation was observed from the ellipsoidal pore-shapes of titania nanotubes grown in aqueous electrolyte to a square-shaped pore structure subsequent to the anneals. 750 °C annealed nanotubes were found t...