Biological templates such as virions or protein assemblies have several surface functional groups that can complicate the elucidation of the fundamental mechanism(s) governing the sorption and mineralization of metals on the surface of the template. Surface functionalized silica nanoclusters with hydroxyl, amine, or thiol groups serve as surrogates for understanding the interaction between indi...

The mechanism, isotherms and kinetics of removal of two endocrine disrupting chemicals, 17β-estradiol (E2) and 17αethinyloestradiol (EE2) by activated carbon adsorption were investigated in an agitated non-flow batch adsorption studies. Mathematical models were used to describe the adsorption phenomenon with the kinetic and thermodynamic parameters evaluated using the adsorption equilibrium dat...

The current work deals with the phenomenon of silver cations uptake by two kinds of bacteria isolated from dairy products. The mechanism of sorption of silver cations by Lactococcus lactis and Lactobacillus casei bacteria was investigated. Inductively coupled plasma-mass spectrometry (ICP-MS) was used for determination of silver concentration sorbed by bacteria. Analysis of charge distribution ...

In this study, the sorption behavior of Zn2+ on calcite, kaolinite, and clinoptilolite, in addition to mixtures of calcite with kaolinite and clinoptilolite, was investigated at various loadings and mixture compositions using atomic absorption spectroscopy, scanning electron microscopy/energy dispersive X-ray spectroscopy, X-ray powder diffraction, and Fourier transform infrared techniques. Acc...

Nanoporous frameworks are polymeric materials built from rigid molecules, which give rise to their nanoporous structures with applications in gas sorption and storage, catalysis and others. Conceptually new applications could emerge, should these beneficial properties be manipulated by external stimuli in a reversible manner. One approach to render nanoporous frameworks responsive to external s...

the vigna subterranean (l.) verdc hull’s (vsvh) potential to remove cr(vi) ions from aqueous solutions was investigated. the biosorbent was characterised by ftir, sem-edx and xrf before and after exposure to cr(vi). the surface comprised of phenolic, carboxylate, sulphonate, carboxyl, ammines, silica, silanol, phosphite esters, alkyl and hydroxyl functional groups responsible for cr(vi) removal...

Renewed focus on the sorption of hydrophobic organic chemicals (HOCs) onto mineral surfaces and soil components is required due to the increased and wider range of organic pollutants being released into the environment. This mini-review examines the possibility of the contribution and mechanism of HOC sorption onto clay mineral sorbents such as kaolinite, and soil organic matter and the possibl...

No. pan0505 Sorption of Heavy Metal Contaminants onto Hydrated Ferric Oxides: Mechanistic Modeling using X-ray Absorption Spectroscopy P. Trivedi, D. Sparks (U. Delaware) and K. Pandya (NRL) Beamline(s): X11A Introduction: Iron oxides are ubiquitous in soils and aquatic sediments as discrete particles or coatings on other mineral and organic materials. They play a significant role in controllin...