Yttria-stabilized zirconia (YSZ) is the best known ceramic-oxide material employed as a component of either solid electrolyte or anode cermet material for intermediate solid oxide fuel cell (IT SOFC). The properties of traditionally produced (by mechanical mixing of oxides) Al2O3/3YSZ composite with the same composition materials obtained by citrate and impregnation methods and with properties ...

A cobalt-based thermoelectric compound Ca(3)Co(2)O(6) (CCO) has been developed as new cathode material with superior performance for intermediate-temperature (IT) solid-oxide fuel cell (SOFC). Systematic evaluation has been carried out. Measurement of thermal expansion coefficient (TEC), thermal-stress (σ) and interfacial shearing stress (τ) with the electrolyte show that CCO matches well with ...

Solid oxide fuel cells (SOFC) are the cleanest, most efficient, and cost-effective option for direct conversion to electricity of a wide variety of fuels. While significant progress has been made in anode materials with enhanced tolerance to coking and contaminant poisoning, cathodic polarization still contributes considerably to energy loss, more so at lower operating temperatures. Here we rep...

This paper presents the work for efficiency enhancement on a hybrid power system with an irreversible Solid Oxide Fuel Cell (SOFC) and Stirling Engine (SE) various design using approach of finite-time thermodynamics. The SOFC-based cogeneration was integrated SE several heat components. effects configurations interface components performance were investigated. By analyzing thermodynamics consid...

Thermal radiation plays a very important role in the heat transfer combination through the various components of the SOFC fuel cell operating at high temperatures. Lattice Boltzmann method is used for treating conduction-radiation heat transfer in the electrolyte. The thermal radiation heat transfer is coupled to the overall energy conservation equations through the divergence of the local radi...

Thermally robust and chemically inert Ag@SiO2 nanoprobes are employed to provide the surface enhanced Raman scattering (SERS) effect for an in situ/operando study of the early stage of carbon deposition on nickel-based solid oxide fuel cell (SOFC) anodes. The enhanced sensitivity to carbon enables the detection of different stages of coking, offering insights into intrinsic coking tolerance of ...

An 8 nm-thick gadolinium-doped ceria (GDC) layer was inserted as a cathodic interlayer between the nanoscale proton-conducting yttrium-doped barium zirconate (BZY) electrolyte and the porous platinum cathode of a micro-solid oxide fuel cell (μ-SOFC), which has effectively improved the cathode reaction kinetics and rendered high cell power density. The addition of the GDC interlayer significantl...

In this paper, a nonlinear offline model of the solid oxide fuel cell (SOFC) is built by using a radial basis function (RBF) neural network based n a genetic algorithm (GA). During the process of modeling, the GA aims to optimize the parameters of RBF neural networks and the optimum alues are regarded as the initial values of the RBF neural network parameters. Furthermore, we utilize the gradie...

Based upon the thermodynamic simulation of a biogas-SOFC integrated process and costing its elements, present work examines economic feasibility biogas-SOFCs for combined heat power (CHP) generation, by comparison their performance against conventional biogas-CHP with internal combustion engines (ICEs), under same assumptions. As well as issues scale an SOFC’s cost, examined in literature, stud...

Record high performance and longevity is reported for a butane-fueled low-temperature-operating solid oxide fuel cell (LT-SOFC). Affordable catalysts, Cu CeO 2 , were incorporated into thin-film-based SOFC to enable this remarkable enhancement.