in this work some quantitative structure activity relationship models were developed for prediction of three bioenvironmental parameters of 28 volatile organic compounds, which are used in assessing the behavior of pollutants in soil. these parameters are; half-life, non dimensional effective degradation rate constant and effective péclet number in two type of soil. the most effective descripto...

The focus of this study is to understand the origin of the chiral recognition for a host-guest system containing complexes with different stoichiometries. Each enantiomer of 2-naphthyl-1-ethanol forms two different 1 : 1 complexes with β-cyclodextrin, leading to the formation of three different 2 : 2 complexes. One of these 2 : 2 complexes leads to excimer emission of the guest. Fluorescence st...

We present simple explicit estimates for the apparent reaction rate constant for threemolecular reactions. For small concentrations and d > 1, it depends only on the diffusion coefficients and sizes of the particles. For small concentrations and d ≤ 1, it is also time – dependent. For large concentrations, it gains the dependence on concentrations. Typeset using REVTEX 1

digestibility if the models are to accurately simulate organic matter transformations in fish ponds. This is especially true for pond management systems that utilize non-conventional feed and fertilizer sources. Munsiri and Boyd (1995) showed that, with the use of a single first-order rate constant to model organic matter degradation, equilibrium conditions were reached in a relatively short ti...

The purpose of this study was to evaluate the effect of heat treatment on the transformation temperatures of K3, K3XF and MTwo endodontic files. DSC was used to investigate the domains of transformation temperatures and how the transformation temperatures vary along the file. The files were analysed as received and subjected to heat treatment. X-ray diffraction analysis was also used to investi...

We measure the decoherence of a spatially separated atomic superposition due to spontaneous photon scattering. We observe a qualitative change in decoherence versus separation as the number of scattered photons increases, and verify quantitatively the decoherence rate constant in the many-photon limit. Our results illustrate an evolution of decoherence consistent with general models developed f...

Here we report the synthesis of storable N-phenylcarbamate palladacycles that showed robust reactivity in the cross-coupling reaction with an alkyne-encoded protein with a second-order rate constant approaching 19 770 ± 930 M(-1) s(-1).