We have designed and synthesized two new diketopyrrolopyrrole (DPP) based organic sensitizers (DPPCA and DPPCN) with the dithiafulvalene (DTF) unit as donor and cyanoacrylic acid/malononitrile as acceptor moieties. These dyes showed excellent efficiency of photocatalytic hydrogen production over a Pt-TiO2 composite via solar-induced water splitting. The sensitizers showed broad absorptions over...

BACKGROUND The antibacterial activity of 21 nm TiO2 nanoparticles (NPs) and particles modified with Garcinia zeylanica (G. zeylanica) against Methicillin resistant Staphylococcus aureus was investigated in the presence and absence of light. RESULTS Surface modification of TiO2 NPs with the adsorption of G. zeylanica extract, causes to shift the absorption edge of TiO2 NPs to higher wavelength...

Pt/TiO2, Ce/TiO2 and binary system PtCe/TiO2 catalysts were prepared by impregnation method and the structural properties of these catalysts were investigated by means of XRD, CO-TPD and UV-vis diffuse reflectance spectroscopy. As investigated by XRD, the composition of the prepared samples anatase and rutile phases with higher amount of anatase phase and its particle size was in the range of 1...

Multi-walled carbon nanotube (MWCNT)/TiO2 mesoporous networks can be employed as a new alternative photoanode in dye-sensitized solar cells (DSSCs). By using the MWCNT/TiO2 mesoporous as photoanodes in DSSC, we demonstrate that the MWCNT/TiO2 mesoporous photoanode is promising alternative to standard FTO/TiO2 mesoporous based DSSC due to larger specific surface area and high electrochemical act...

Current industrial catalysts for the water-gas shift reaction are commonly mixtures of Fe-Cr and Zn-Al-Cu oxides, used at temperatures between 350-500oC and 180250oC, respectively. These oxide catalysts are pyrophoric and normally require lengthy and complex activation steps before usage. Improved catalysts are being sought, particularly for lower temperature (e.g., at T<150oC, equilibrium lowe...

Recent advances in synthetic materials sciences such as the incorporation of self-assembly, sol–gel, and layer-by-layer deposition chemistry have afforded the development of many interesting and potentially useful nanostructures. Among those, nanoarchitectures in which a core nanoparticle, often a transition metal, is encapsulated by an outer layer of a second material, typically a porous oxide...

The water–gas shift (WGS) activity of Pt/TiO2-based powdered and structured catalysts was investigated using realistic feed compositions that are relevant to the high-temperature (HTS) low-temperature (LTS) reaction conditions. promotion TiO2 support with small amounts alkali- or alkaline earth-metals resulted in enhancement WGS 0.5%Pt/TiO2(X) (X = Na, Cs, Ca, Sr). use bimetallic (Pt–M)/TiO2 (M...

in this paper, a modified sol-gel method using peroxotitanic acid sol (pta) was applied for the preparation of tio2 nanostructured thin films on glass plates. the peroxotitanic acid sol was synthesized using titanium isopropoxide, isopropylalchol, h2o and hydrogen peroxide. tio2 films were then calcined at 500oc and characterized by x-ray diffraction (xrd) and scanning electron microscopy (sem)...

Flame spray-synthesized Pt/TiO2 and PtCo/TiO2 catalysts with 0.7 wt% Pt 0–0.4 Co were studied in the hydrogenation of furfural to furfuryl alcohol (FA) at 50 °C 2 MPa H2. Particle formation under high temperature flame facilitated dispersion Pt-TiOx interface sites, which beneficial for conversion FA. Modifying accelerated rutile phase TiO2 formation, strongly diminished activity on (FSP)-PtCo/...

Hot holes in Pt-Cu alloy clusters can act as catalyst to accelerate the intrinsic aerobic oxidation reactions. It is described that under visible light irradiation the synergistic alcohol catalytic oxidation on Pt-Cu alloy clusters (≈1.1 nm)/TiO2 nanobelts could be significant promoted by interband-excitation-generated long-lifetime hot holes in the clusters.