Samples taken during deuteration of methyl linoleate with the title catalysts were separated into saturate, monoene and diene fractions. Monoenes were further separated into cis and trans fractions. A comparison of the double bond distribution in monoenes with those from hydrogenation of alkaliconjugated !inoleate indicated that up to 59% of the !inoleate was reduced through a conjugated interm...

First-row metal complexes often undergo undesirable one-electron redox processes during two-electron steps of catalytic cycles. We report the amination of aryl chlorides and bromides with primary aliphatic amines catalyzed by a well-defined, single-component nickel precursor (BINAP)Ni(η(2)-NC-Ph) (BINAP = 2,2'-bis(biphenylphosphino)-1,1'-binaphthalene) that minimizes the formation of Ni(I) spec...

Selecting a proper support in the catalyst system plays an important role in hydrogen production via ethanol steam reforming. In this study, sol gel made alumina supports prepared for nickel (Ni) catalysts were calcined at different temperatures. A series of (Ni/AlS.G.) catalysts were synthesized by an impregnation procedure. The influence of varying the calcination temperature of the sol gel m...

The deactivation pattern of a “model” Ni/MgO catalyst in the pre-reforming of n-hexane with steam (T, 450 °C; P, 5–15 bar) is reviewed. The influence of the steam-to-carbon ratio (S/C, 1.5–3.5) on the rate of catalyst fouling by coking is ascertained. Catalyst fouling leads to an exponential decay in activity, denoting 1-order dependence of the coking process on active sites availability. Hydro...

Copper and nickel hydrogenations give a wide distribution of double bonds in the monoene fraction from both reduced soybean and linseed oils. With copper catalysts, high pressure hydrogenation reduces the extent of this double bond distribution when compared with low pressure hydrogenation. With nickel catalysts, some t.17-octadecenoate is formed but less than with a copper catalyst. In room od...

Catalytically graphitized electrospun carbon nanofibers adorned uniformly with fine nickel nanoparticles were successfully prepared. The procedure was based on the electrospinning technique and the use of nickel precursor to create both graphitized nanofibers and nickel nanoparticles under a relatively low-temperature heat treatment. The X-ray diffraction and Raman results clearly proved cataly...

The growth behavior of carbon nanotubes synthesized from C2H2 at the temperature range of 700 to 900°C and using thermal chemical vapor deposition (TCVD) method has been investigated. Thin films of nickel (Ni) catalyst, were coated on SiO2 substrates by ion beam sputtering technique. The formation of catalytic nickel nanoparticles was much increased when using NH3 as the environment gas which i...

Iron doping of nickel oxide films results in enhanced activity for promoting the oxygen evolution reaction (OER). Whereas this enhanced activity has been ascribed to a unique iron site within the nickel oxide matrix, we show here that Fe doping influences the Ni valency. The percent of Fe3+ doping promotes the formation of formal Ni4+, which in turn directly correlates with an enhanced activity...

Single crystal catalysts have been used to investigate ethane hydrogenolysis. The apparatus used in these studies allows for catalyst preparation and surface characterization in ultrahigh vacuum (UHV) with an in vacua transfer to a second UHV chamber designed for high pressure kinetic studies. Kinetic measurements on single crystals of nickel show the hydrogenolysis of ethane to be “structure s...

In this study, we examined a scale-up to production of nickel perovskite catalyst, used in the conversion of natural gas to synthesis gas, using the sol-gel method in the laboratory and a bench-scale reactor. The required volume of solvent and catalyst activity in the methane-reforming reaction was determined from the optimum catalyst production conditions at the laboratory scale. This informat...