Haloalkane dehalogenase converts haloalkanes to their corresponding alcohols. The 3D structure, reaction mechanism and kinetic mechanism have been studied. The steady state k(cat) with 1,2-dichloroethane and 1,2-dibromoethane is limited mainly by the rate of release of the halide ion from the buried active-site cavity. During catalysis, the halogen that is cleaved off (Cl alpha) from 1,2-dichlo...

ABSTRACT A program is developed that includes two hydrodynamic models, a 2D depth-averaged (2DH) and a Quasi-3D (Q3D), and a pollutant transport model that uses a 1 order upwinding and a 3 order QUICKEST numerical schemes. Several tests were performed in two test basins in order to examine the performance of the above models. The Q3D model is successfully applied to Lake Ontario, using a 4-km-s...

The dehalogenases make use of fundamentally different strategies to cleave carbon-halogen bonds. The structurally characterized haloalkane dehalogenases, haloacid dehalogenases and 4-chlorobenzoate-coenzyme A dehalogenases use substitution mechanisms that proceed via a covalent aspartyl intermediate. Recent X-ray crystallographic analysis of a haloalcohol dehalogenase and a trans-3-chloroacryli...

Plants are increasingly being employed to clean up environmental pollutants such as heavy metals; however, a major limitation of phytoremediation is the inability of plants to mineralize most organic pollutants. A key component of organic pollutants is halogenated aliphatic compounds that include 1,2-dichloroethane (1,2-DCA). Although plants lack the enzymatic activity required to metabolize th...

This study proposes a framework for estimating pollutant flux in an estuary. An efficient method is applied to estimate the flux of pollutants in an estuary. A gauging station network in the Danshui River estuary is established to measure the data of water quality and discharge based on the efficient method. A boat mounted with an acoustic Doppler profiler (ADP) traverses the river along a pres...

BACKGROUND Toxic substances released into the environment (to both air and water) by many types of industries might be related with the occurrence of some malignant tumours and other diseases. The publication of the EPER (European Pollutant Emission Register) Spanish data allows to investigate the presence of geographical mortality patterns related to industrial pollution. The aim of this paper...

This paper presents a novel Neural Network application in order to estimate Air Pollutant Levels. The application considers both Pollutant concentrations and Meteorological variables. In order to compute the Air Pollutant Level the method considers three important stages. In first stage, A process to validate data information and built a threedimensional Information Feature Vector with Pollutan...