Synthesis, characterization, and textile application of novel disperse dyes
نویسندگان
چکیده مقاله:
In this paper, two novel alkali clearable disperse dyes were synthesized. 4-flourosulfonyl aniline and 2-nitro-4-flourosulfonyl aniline were utilized as the diazo components and 2- naphthol as the coupling component. The DSC, FTIR, 1HNMR and UV-Vis analyses were used to characterize the synthesized intermediates and dyes. The synthesized dyes were used to dye polyester fibers and their dyeing properties were studied. In addition, hydrolysis kinetic of the synthesized dyes in alkali media was studied. The results showed that the synthesized dyes have good properties on polyester fabrics. Hydrolysis of the synthesized dyes in alkaline media provides the replacement of reduction clearing process by alkali-clearing process. The elimination of sodium hydrosulphite will cause reduction of environmental pollution. The advantage of replacement of reduction clearing-method by alkali-clearing process will cause the prevention of producing toxic and carcinogenic compounds.
منابع مشابه
synthesis and characterization of some macrocyclic schiff bases
ماکروسیکلهای شیف باز از اهمیت زیادی در شیمی آلی و دارویی برخوردار می باشند. این ماکروسیکلها با دارابودن گروه های مناسب در مکانهای مناسب می توانند فلزاتی مثل مس، نیکل و ... را در حفره های خود به دام انداخته، کمپلکسهای پایدار تولید نمایند. در این پایان نامه ابتدا یک دی آلدئید آروماتیک از گلیسیرین تهیه می شود و در مرحله بعدی واکنش با دی آمینهای آروماتیک و یا آلیفاتیک در رقتهای بسیار زیاد منجر به ت...
15 صفحه اولSynthesis of some novel pyrazolo[1,5-a]pyrimidine derivatives and their application as disperse dyes.
A series of novel monoazo-disperse dyes containing pyrazolo[1,5-a]pyrimidine structures were synthesized starting with the coupling reaction between ethyl cyanoacetate and 4-hydroxybenzenediazonium chloride, followed by treatment of the resulting hydrazone product with hydrazine hydrate. The pyrazolohydrazone 6 is then treated with either 2,4-pentandione and enaminonitrile or aryl-substituted e...
متن کاملextraction and characterization of allium irancum plant extract and its application in the green synthesis of silver nano particles and oxidation of thiocarbony1 compounds
سنتز سبز نانوذرات فلزی (nps) درسالهای اخیر توجه بسیارزیادی را به خود جلب کرده است. زیرا این پروتوکل کم هزینه وسازگار با محیط زیست از روش های استاندارد سنتز. در این پایان نامه ما گزارش میکنیم یک روش ساده و سازگار با محیط زیست برای سنتز نانوذرات نقره با استفاده از محلول آبی عصاره گیاه allium iranicum به عنوان یک عامل کاهش دهنده ی طبیعی. نانو ذرات نقره مشخص شد با استفاده از تکنیک های uv-visible، x...
Dyeing of Polyester with Disperse Dyes: Part 2. Synthesis and Dyeing Characteristics of Some Azo Disperse Dyes for Polyester Fabrics.
The goal of this study was to utilize carrier for accelerating the rate of dyeing not only to enhance dyeing of polyester fabrics dyed with disperse dyes 3a,b, but also to save energy. Both the color strength expressed as dye uptake and the fastness properties of the dyed fabrics were evaluated.
متن کاملSynthesis of Novel Reactive Disperse Silicon-Containing Dyes and Their Coloring Properties on Silicone Rubbers.
Novel red and purple reactive disperse silicon-containing dyes were designed and synthesized using p-nitroaniline and 6-bromo-2,4-dinitro-aniline as diazonium components, the first condensation product of cyanuric chloride and 3-(N,N-diethyl)amino-aniline as coupling component, and 3-aminopropylmethoxydimethylsilane, 3-aminopropylmethyldimethoxysilane, and 3-aminopropyltrimethoxysilane as silic...
متن کاملDyeing with Disperse Dyes
Before the First World War, almost all dyes were applied from solution in an aqueous dyebath to substrates such as cotton, wool, silk and other natural fibres. However, the introduction of a man-made fibre, cellulose acetate, with its inherent hydrophobic nature, created a situation where very few of the available dyes had affinity for the new fibre. Water-soluble anionic dyes had little substa...
متن کاملمنابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ذخیره در منابع من قبلا به منابع من ذحیره شده{@ msg_add @}
عنوان ژورنال
دوره 7 شماره 3
صفحات 155- 163
تاریخ انتشار 2013-09-20
با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023