Synthesis and characterization of Polyvinyl Alcohol-Polypyrrole-Silver nanocomposite polymer films

نویسندگان

  • Dattatray Nerkar Department of Physics, Sathaye College, Dixit Road, Vile Parle (East), Mumbai 400057, India.
  • Madhav Rajwade Department of Physics, Sathaye College, Dixit Road, Vile Parle (East), Mumbai 400057, India.
  • Milind Jog Kirti M. Doongursee College, Dadar (West), Mumbai 400028, India.
  • Suryakant Jaware Department of Physics, Sathaye College, Dixit Road, Vile Parle (East), Mumbai 400057, India.
چکیده مقاله:

The present paper describes the preparation and characterization of Polyvinyl Alcohol-Polypyrrole-Silver Nanocomposite (PVA-PPy-Ag NC) films. The prepared films were conducting, freestanding, flexible, and robust. Silver nanoparticles (Ag NPs) were synthesized from an aqueous solution of silver nitrate using trisodium citrate as a reductant. The casting solution for the films was prepared by in-situ chemical oxidative polymerization of pyrrole. This was done in the presence of Polyvinyl Alcohol and suspension of pre-synthesized silver nanoparticles. The absorption band at 424 nm in UV-Visible Spectroscopy of silver nanoparticles confirmed the formation of Ag nanoparticles. Scanning Electron Microscopy (SEM) studies revealed that spherical Ag NPs were produced with an average size of ~ 25 nm. The morphological analysis of the synthesized PVA-PPy-Ag nanocomposite films was carried out using Transmission Electron Microscopy (TEM). It was observed in the TEM images that Ag nanoparticles were well dispersed and conjugated in the PVA-PPy matrix. The structure of the produced films was studied by Fourier transform infrared (FTIR) Spectroscopy and X-Ray Diffraction (XRD). X-ray diffraction analysis exhibited the crystalline nature of the silver nanoparticles with a face-centered cubic (fcc) structure. The synthesized PVA-PPy-Ag nanocomposite films can be further utilized as potential material for the fabrication of gas sensors.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Polypyrrole/Silver Nanocomposite: Synthesis, Characterization and Antibacterial Activity

Polypyrrole/silver (PPy/Ag)nanocomposite was synthesized by a chemical oxidative method. SEM and TEM analyses were performed for studying the morphology of the nanocomposite. It was shown that the obtained nanocomposite particles have a spherical structure with the high surface area to volume ratio that is the important factor in the biological application. The particle sizes of the P...

متن کامل

Synthesis and characterization of chitosan–silver nanocomposite

Chitosan–silver (CS–Ag) nanocomposite materials were synthesized by a simple chemical method. The synthesized CS–Ag nanocomposite contains 20 wt% silver. Silver nanoparticles were synthesized by chemical reduction method as well. The CS–Ag nanocomposite was characterized using Field emission scanning electronic microscope (FESEM), X-ray diffraction (XRD) and Fourier transform infrared spectrosc...

متن کامل

Micropatterning of silver nanoclusters embedded in polyvinyl alcohol films.

Direct laser writing has been utilized to fabricate highly photostable fluorescent nanocluster microstructures in an organic polymer poly(methacrylic acid), where the carboxyl functional group is reported to play a vital role in nanocluster stabilization. In this Letter, we demonstrate that not only the polymer containing the carboxyl functional group, but also the polymer comprising the hydrox...

متن کامل

Effects of ultrasound time on the properties of polyvinyl alcohol-based nanocomposite films

Background and Objectives: Preparation and evaluation of nanocomposite films have become prevalent in recent years. One of the most important methods for dispersing nanoparticles in polymers is the use of ultrasound radiation. Polyvinyl alcohol-montmorillonite (PVA-MMT) nanocomposite films were prepared via solvent casting method. Materials and Methods: The effects of different ultrasound ti...

متن کامل

Synthesis and Characterization of Silver Nanocomposite as a Food Packaging

Today nanopackaging has been applied in order to increase the quality and safety of foods. In this study the possibility of using silver nanocomposite as food packaging is investigated. Silver nanoparticles were prepared by chemical reduction and to approve the presence of silver nanoparticles, UV-VS spectroscopy was used. The mentioned test showed the formation of silver nanoparticles by exhib...

متن کامل

extraction and characterization of allium irancum plant extract and its application in the green synthesis of silver nano particles and oxidation of thiocarbony1 compounds

سنتز سبز نانوذرات فلزی (nps) درسالهای اخیر توجه بسیارزیادی را به خود جلب کرده است. زیرا این پروتوکل کم هزینه وسازگار با محیط زیست از روش های استاندارد سنتز. در این پایان نامه ما گزارش میکنیم یک روش ساده و سازگار با محیط زیست برای سنتز نانوذرات نقره با استفاده از محلول آبی عصاره گیاه allium iranicum به عنوان یک عامل کاهش دهنده ی طبیعی. نانو ذرات نقره مشخص شد با استفاده از تکنیک های uv-visible، x...

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 11  شماره 3

صفحات  205- 214

تاریخ انتشار 2020-07-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023