Nano-TiCl4.SiO2: A Versatile and Efficient Catalyst for Synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes

نویسندگان

  • A. Bamoniri Deprtment of Organic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, I. R. Iran.
  • B. F. Mirjalili Department of Chemistry, College of Science, Yazd University, Yazd, PO Box 89195-741, I. R. Iran.
  • L. Zamani Department of Chemistry, College of Science, Yazd University, Yazd, PO Box 89195-741, I. R. Iran.
چکیده مقاله:

Nano-silica supported titanium tetrachloride (TiCl4.SiO2) was prepared and used as an acid catalyst for the 14-aryl or alkyl-14H-dibenzo[a,,j]xanthenesreaction under solvent-free conditions. Compared to the classical 14-aryl or alkyl-14H-dibenzo[a,j]xanthenesreaction conditions, this method consistently has the advantage of excellent yields, mild reaction conditions, ease of workup, survival of different functional groups and short reaction times.

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nano-ticl4.sio2: a versatile and efficient catalyst for synthesis of 14-aryl or alkyl-14h-dibenzo[a,j]xanthenes

nano-silica supported titanium tetrachloride (ticl4.sio2) was prepared and used as an acid catalyst for the 14-aryl or alkyl-14h-dibenzo[a,,j]xanthenesreaction under solvent-free conditions. compared to the classical 14-aryl or alkyl-14h-dibenzo[a,j]xanthenesreaction conditions, this method consistently has the advantage of excellent yields, mild reaction conditions, ease of workup, survival of...

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عنوان ژورنال

دوره 3  شماره 4

صفحات  461- 466

تاریخ انتشار 2013-12-01

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