An Efficient Pd-Sn Catalyst Supported on MWNTs for Hydrogenation of High Concentrated Acetylene Feedstocks: The Potential Role of Isolated Adsorption Site

نویسندگان

  • A. Rashidi Nano Research Center, Research Institute of Petroleum Industry (RIPI), P.O. Box 18745/4163, Tehran, Iran.
  • E. Esmaeili Department of Chemical Engineering, Birjand University of Technology, P.O. Box 97175/569, Birjand, Iran.
چکیده مقاله:

In the present study, tin-promoted Pd/MWNTs nanocatalystwas synthesized via polyol technique for application in hydrogenation of high-concentrated acetylene feedstocks. TEM images showed a restricted distribution of nanoparticles in the range of 3-5 nm. The results indicated that nanoparticles sizes were resistant to further catalyst deactivation. XRD patterns signified alloying between Pd and Sn which contained a high percentage of ordered intermetallic structures (70.8%), as confirmed by XPS. According to the results, pore blocking and/or fouling was known as the main reasons of the catalyst deactivation. Here, we supposed a novel deactivation mechanism based on which dehydrogenation susceptibility of carbonaceous species (green oil) played a significant role in the formation of the isolated adsorption sites and then, catalyst deactivation.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

an efficient pd-sn catalyst supported on mwnts for hydrogenation of high concentrated acetylene feedstocks: the potential role of isolated adsorption site

in the present study, tin-promoted pd/mwnts nanocatalystwas synthesized via polyol technique for application in hydrogenation of high-concentrated acetylene feedstocks. tem images showed a restricted distribution of nanoparticles in the range of 3-5 nm. the results indicated that nanoparticles sizes were resistant to further catalyst deactivation. xrd patterns signified alloying between pd and ...

متن کامل

Role of the Mg/Al atomic ratio in hydrotalcite-supported Pd/Sn catalysts for nitrate adsorption and hydrogenation reduction.

Hydrotalcite-supported Pd/Sn catalysts with different Mg/Al atomic ratios (2, 3, 4, and 5) for nitrate adsorption and hydrogenation reduction were successfully synthesized by a coprecipitation method. The results showed that different atomic ratios of Mg/Al resulted in different interlayer spacings and zeta-potentials of the catalysts, which thus influenced its adsorption capacity. With the inc...

متن کامل

Pd and Fe3O4 Nanoparticles Supported on ‎N-(2-Aminoethyl)Acetamide Functionalized ‎Cellulose as an Efficient Catalyst for ‎Epoxidation of Styrene

A new efficient heterogeneous catalyst was introduced for the epoxidation of styrene. The catalyst was obtained from functionalization of cellulose with N-(2-aminoethyl)acetamide, and then deposition of nanoparticles and Pd(0) nanoparticles on the modified cellulose. The Fe3O4 nanoparticles were deposited via chemical oxidation in basic media and Pd(0) nanoparticles we...

متن کامل

focus on communication in iranian high school language classes: a study of the role of teaching materials in changing the focus onto communication in language classes

چکیده ارتباط در کلاس به عوامل زیادی از جمله معلمان، دانش آموزان، برنامه های درسی و از همه مهم تر، مواد آموزشی وابسته است. در تدریس ارتباطی زبان که تاکید زیادی بر توانش ارتباطی دارد، کتاب درسی به عنوان عامل موثر بر پویایی کلاس محسوب میگردد که درس ها را از طریق فراهم آوردن متن ارتباط کلاسی و هم چنین نوع تمرین زبانی که دانش آموزان در طول فعالیت های کلاسی به آن مشغول اند، کنترل می کند. این حقیقت ک...

15 صفحه اول

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 4  شماره 2

صفحات  133- 144

تاریخ انتشار 2014-04-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023